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Which of the following molecules or ions...

Which of the following molecules or ions is a bidentate ligand ?

A

`C_(2)O_(4)^(2-)`

B

`Br^(2+)`

C

`CH_(3)NH_(2)`

D

`CH_(3)-C-=N`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given molecules or ions is a bidentate ligand, we first need to understand what a bidentate ligand is. A bidentate ligand is a molecule or ion that can donate two pairs of electrons (two lone pairs) to a metal atom or ion, forming two coordinate bonds. ### Step-by-Step Solution: 1. **Identify the Options**: We need to look at the options provided in the question. For this example, let’s assume the options are: - A) C2O4^2- (Oxalate ion) - B) CH3NH2 (Methylamine) - C) CH3CN (Acetonitrile) - D) NH3 (Ammonia) 2. **Analyze Each Option**: - **Option A: C2O4^2- (Oxalate ion)**: - The oxalate ion has two oxygen atoms that can donate lone pairs to a metal center. Each of these oxygen atoms has a lone pair of electrons that can be used for bonding. Therefore, oxalate is a bidentate ligand. - **Option B: CH3NH2 (Methylamine)**: - Methylamine has one nitrogen atom that can donate a lone pair. It can only form one coordinate bond with a metal center, making it a monodentate ligand. - **Option C: CH3CN (Acetonitrile)**: - Acetonitrile has one nitrogen atom that can donate a lone pair. Similar to methylamine, it can only form one coordinate bond, thus it is also a monodentate ligand. - **Option D: NH3 (Ammonia)**: - Ammonia has one nitrogen atom that can donate a lone pair. It is also a monodentate ligand since it can only form one coordinate bond. 3. **Conclusion**: After analyzing all the options, we find that the only bidentate ligand among the given choices is **C2O4^2- (Oxalate ion)**. ### Final Answer: The bidentate ligand is **C2O4^2- (Oxalate ion)**.

To determine which of the given molecules or ions is a bidentate ligand, we first need to understand what a bidentate ligand is. A bidentate ligand is a molecule or ion that can donate two pairs of electrons (two lone pairs) to a metal atom or ion, forming two coordinate bonds. ### Step-by-Step Solution: 1. **Identify the Options**: We need to look at the options provided in the question. For this example, let’s assume the options are: - A) C2O4^2- (Oxalate ion) - B) CH3NH2 (Methylamine) ...
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