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Assertion (A) : B(2)H(6),Si2H(6) are sai...

Assertion (A) : `B_(2)H_(6),Si2H_(6)` are said to have similar structure .
Reason (R) : They have same number of `sigma` and `pi` bonds.

A

If both A and R are true and R is the correct explanation of A.

B

If both A and R are true but R is not the correct explanation of A.

C

If A is true but R is false

D

If A is false but R is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question, we will analyze both the assertion (A) and the reason (R) step by step. ### Step 1: Understanding the Assertion The assertion states that \( B_2H_6 \) (diborane) and \( Si_2H_6 \) (disilane) have similar structures. - **Diborane Structure**: - Diborane consists of two boron atoms and six hydrogen atoms. Each boron atom undergoes \( sp^3 \) hybridization, resulting in four orbitals. - In diborane, there are four sigma bonds formed: three \( B-H \) bonds and one \( B-B \) bond, which involves a three-center two-electron bond (banana bond). - **Disilane Structure**: - Disilane consists of two silicon atoms and six hydrogen atoms. Each silicon atom also undergoes \( sp^3 \) hybridization. - In disilane, there are four sigma bonds formed: three \( Si-H \) bonds and one \( Si-Si \) bond. ### Step 2: Analyzing the Reason The reason states that \( B_2H_6 \) and \( Si_2H_6 \) have the same number of sigma and pi bonds. - **Sigma Bonds**: - In \( B_2H_6 \), there are 4 sigma bonds (3 \( B-H \) and 1 \( B-B \)). - In \( Si_2H_6 \), there are also 4 sigma bonds (3 \( Si-H \) and 1 \( Si-Si \)). - **Pi Bonds**: - Neither diborane nor disilane has pi bonds in their structures. Therefore, both have 0 pi bonds. ### Conclusion - The assertion is **true** because both compounds have similar structures due to \( sp^3 \) hybridization. - The reason is **false** because while they have the same number of sigma bonds, they do not have the same number of pi bonds (both have 0, but the reason implies a comparison that is not valid). Thus, the correct conclusion is that the assertion is true, but the reason is false. ### Final Answer - Assertion (A) is true. - Reason (R) is false.

To solve the assertion and reason question, we will analyze both the assertion (A) and the reason (R) step by step. ### Step 1: Understanding the Assertion The assertion states that \( B_2H_6 \) (diborane) and \( Si_2H_6 \) (disilane) have similar structures. - **Diborane Structure**: - Diborane consists of two boron atoms and six hydrogen atoms. Each boron atom undergoes \( sp^3 \) hybridization, resulting in four orbitals. - In diborane, there are four sigma bonds formed: three \( B-H \) bonds and one \( B-B \) bond, which involves a three-center two-electron bond (banana bond). ...
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