Home
Class 12
CHEMISTRY
Assertion : Phenol is a weak acid than ...

Assertion : Phenol is a weak acid than ethanol.
Reason : Groups with +M effect and -I effect decrease acidity at m-position .

A

If both the assertion and reason are true and reason is correct explanation of the assertion .

B

If both the assertion and reason are true but reason is not a correct explanation of the assertion .

C

If the assertion is true but the reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Phenol is a weaker acid than ethanol." - To evaluate this, we need to consider the acidity of both compounds. Phenol (C6H5OH) can donate a proton (H+) to form the phenoxide ion (C6H5O-), which is resonance-stabilized. Ethanol (C2H5OH), on the other hand, can donate a proton to form the ethoxide ion (C2H5O-), which is not resonance-stabilized. - Since the phenoxide ion is more stable due to resonance, phenol is actually a stronger acid than ethanol. 2. **Understanding the Reason**: - The reason states that "Groups with +M effect and -I effect decrease acidity at m-position." - The +M (mesomeric) effect refers to the ability of certain groups to donate electron density through resonance, while the -I (inductive) effect refers to the withdrawal of electron density through sigma bonds. - The statement about the m-position is misleading because groups with +M effect typically increase acidity by stabilizing the negative charge on the conjugate base, while -I effect groups can decrease acidity by destabilizing the conjugate base. However, the assertion does not relate directly to the reason provided. 3. **Conclusion**: - Since the assertion is false (phenol is a stronger acid than ethanol) and the reason is also false (it does not correctly explain the assertion), we conclude that both the assertion and the reason are incorrect. ### Final Answer: Both assertion and reason are false.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "Phenol is a weaker acid than ethanol." - To evaluate this, we need to consider the acidity of both compounds. Phenol (C6H5OH) can donate a proton (H+) to form the phenoxide ion (C6H5O-), which is resonance-stabilized. Ethanol (C2H5OH), on the other hand, can donate a proton to form the ethoxide ion (C2H5O-), which is not resonance-stabilized. - Since the phenoxide ion is more stable due to resonance, phenol is actually a stronger acid than ethanol. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Phenol is more acidic than :

Phenol is less acidic than

Phenol is less acidic than

Phenol is less acidic than

Phenol is less acidic than

More acidic than ethanol is

Phenol is a weaker acid than acetic acid because:

Assertion : Phenol is more acidic then m-methoxy phenol Reason : -OCH_(3) shows +I effect

Assertion : Hydroquinone is more acidic than resorcinol. Reason : OH shows -I effect