Home
Class 12
CHEMISTRY
Assertion : Alkyl benzene is not prepare...

Assertion : Alkyl benzene is not prepared by Friedel Craft alkylation of benzene.
Reason : Grignard reagents react with hydroxyl group

A

If the both assertion and reason are true and the reason is the correct explanation of the assertion

B

If both assertion and reason are true and the reason is not the correct explanation of the assertion

C

If assertion is false but reason is true

D

If both assertion and reason are false statements.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states: "Alkyl benzene is not prepared by Friedel Craft alkylation of benzene." - Friedel-Crafts alkylation is a well-known reaction where an alkyl group is introduced to an aromatic ring (like benzene) using an alkyl halide and a Lewis acid catalyst (such as AlCl3). - For example, if we take benzene and react it with ethyl chloride (C2H5Cl) in the presence of anhydrous AlCl3, the ethyl group can successfully be attached to the benzene ring, resulting in ethyl benzene. **Conclusion for Step 1**: The assertion is **false** because alkyl benzene can indeed be prepared via Friedel-Crafts alkylation. ### Step 2: Analyze the Reason The reason states: "Grignard reagents react with hydroxyl group." - Grignard reagents (RMgX) are highly reactive organomagnesium compounds that can react with various functional groups. - When Grignard reagents encounter alcohols (which contain hydroxyl groups, -OH), they undergo an acid-base reaction. The acidic hydrogen of the hydroxyl group reacts with the Grignard reagent, leading to the formation of an alkoxide and releasing a hydrocarbon (alkane) as a byproduct. **Conclusion for Step 2**: The reason is **true** because Grignard reagents do indeed react with hydroxyl groups. ### Final Conclusion - The assertion is **false**. - The reason is **true**. Thus, the correct answer to the question is that the assertion is false and the reason is true. ### Answer: C (Assertion is false, Reason is true) ---

To solve the question, we need to evaluate both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states: "Alkyl benzene is not prepared by Friedel Craft alkylation of benzene." - Friedel-Crafts alkylation is a well-known reaction where an alkyl group is introduced to an aromatic ring (like benzene) using an alkyl halide and a Lewis acid catalyst (such as AlCl3). - For example, if we take benzene and react it with ethyl chloride (C2H5Cl) in the presence of anhydrous AlCl3, the ethyl group can successfully be attached to the benzene ring, resulting in ethyl benzene. ...
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

Friedel - Crafts alkylation

Friedel - Crafts alkylation

Knowledge Check

  • A Friedel-Crafts reaction of benzene with chloroform produces :

    A
    `C_(6)H_(5)CHCl_(2)`
    B
    `C_(6)H_(5) - oversetoverset(Cl)(|)undersetunderset(H)(|)C-C_(6)H_(5)`
    C
    `C_(6)H_(5) - oversetoverset(C_(6)H_(5))(|)undersetunderset(H)(|)C-C_(6)H_(5)`
    D
    all of these
  • Assertion: Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom. Reason: Phenols react with halogen acids violently.

    A
    If both assertion and reason are true and reason Is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assetion is true but reason is false.
    D
    If both assertion and reason are false.
  • Similar Questions

    Explore conceptually related problems

    Friedel - Crafts alkylation

    Assertion: Hydroxyketones are not directly used in Grignard reaction. Reason : Griganard reagnts react with hydroxyl group.

    Name the reagent used in the Friedel Craft's alkylation of anisole.

    Assertion (A) : MeMgBr should be preapared under perfectly anhydrous conditions. Reason (R): Grinard reagent reacts with water.

    The Friedel-Crafts methylation of benzene involves ..........

    Assertion : Aniline does not undergo Friendel-Crafts reaction . Reason : Friedel-Craft reaction is an electrophilic substitution reaction .