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For reaction aA rarr xP, when [A] = 2.2 ...

For reaction `aA rarr xP`, when `[A] = 2.2 mM`, the rate was found to be `2.4mM s^(-1)`. On reducing concentration of `A` to half, the rate changes to `0.6 mM s^(-1)`. The order of reaction with respect to `A` is

A

`1.5`

B

`2.0`

C

`2.5`

D

`3.0`

Text Solution

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The correct Answer is:
To determine the order of the reaction with respect to A, we can use the information provided about the rates and concentrations of A. ### Step-by-Step Solution: 1. **Identify Given Information:** - Initial concentration of A, \([A]_1 = 2.2 \, \text{mM}\) - Initial rate, \(R_1 = 2.4 \, \text{mM/s}\) - New concentration of A, \([A]_2 = \frac{2.2}{2} = 1.1 \, \text{mM}\) - New rate, \(R_2 = 0.6 \, \text{mM/s}\) 2. **Set Up the Rate Law:** The rate of reaction can be expressed as: \[ R = k [A]^n \] where \(k\) is the rate constant and \(n\) is the order of the reaction with respect to A. 3. **Write Two Equations for the Two Conditions:** For the first condition: \[ R_1 = k [A]_1^n \implies 2.4 = k (2.2)^n \quad \text{(Equation 1)} \] For the second condition: \[ R_2 = k [A]_2^n \implies 0.6 = k (1.1)^n \quad \text{(Equation 2)} \] 4. **Divide Equation 1 by Equation 2:** \[ \frac{R_1}{R_2} = \frac{k (2.2)^n}{k (1.1)^n} \] This simplifies to: \[ \frac{2.4}{0.6} = \frac{(2.2)^n}{(1.1)^n} \] \[ 4 = \left(\frac{2.2}{1.1}\right)^n \] 5. **Simplify the Fraction:** \[ \frac{2.2}{1.1} = 2 \] So we have: \[ 4 = 2^n \] 6. **Solve for n:** Since \(4 = 2^2\), we can equate the exponents: \[ n = 2 \] ### Conclusion: The order of the reaction with respect to A is **2**.

To determine the order of the reaction with respect to A, we can use the information provided about the rates and concentrations of A. ### Step-by-Step Solution: 1. **Identify Given Information:** - Initial concentration of A, \([A]_1 = 2.2 \, \text{mM}\) - Initial rate, \(R_1 = 2.4 \, \text{mM/s}\) - New concentration of A, \([A]_2 = \frac{2.2}{2} = 1.1 \, \text{mM}\) ...
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