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CH(3) CO(2) C(2) H(5) on reaction with s...

`CH_(3) CO_(2) C_(2) H_(5)` on reaction with sodium ethoxide in ethanol gives `A`, which on heating in the presence of acid gives `B` compound `B` is

A

`CH_(3)COCH_(2)COOH`

B

`CH_(3)COCH_(3)`

C

D

Text Solution

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To solve the problem, we need to identify the compounds A and B formed in the reactions involving the ester CH₃COOC₂H₅ (ethyl acetate) with sodium ethoxide in ethanol, and then the subsequent reaction of compound A in the presence of acid. **Step 1: Identify the starting compound.** The starting compound is given as CH₃COOC₂H₅, which is ethyl acetate. **Step 2: Reaction with sodium ethoxide.** When ethyl acetate reacts with sodium ethoxide (C₂H₅ONa) in ethanol, it undergoes a condensation reaction. The sodium ethoxide acts as a base and deprotonates the hydrogen atom adjacent to the carbonyl group of the ester, leading to the formation of a β-keto ester. The reaction can be represented as follows: \[ \text{CH}_3COOC_2H_5 + \text{C}_2H_5ONa \rightarrow \text{CH}_3C(OH)(C_2H_5)COOC_2H_5 \] This compound is labeled as A. The structure of compound A is: \[ \text{CH}_3C(OH)(C_2H_5)COOC_2H_5 \] **Step 3: Heating compound A in the presence of acid.** When compound A is heated in the presence of acid, it undergoes dehydration and rearrangement to form a cyclic compound. The reaction leads to the formation of a compound that has a double bond and a cyclic structure. The reaction can be represented as follows: \[ \text{A} \xrightarrow{\text{heat, acid}} \text{B} \] The structure of compound B can be represented as: \[ \text{C}_5H_8O_2 \text{ (a cyclic compound)} \] **Final Answer:** - Compound A: CH₃C(OH)(C₂H₅)COOC₂H₅ - Compound B: A cyclic compound with a double bond, specifically a compound like 2,5-dimethyl-2,5-dihydrofuran.

To solve the problem, we need to identify the compounds A and B formed in the reactions involving the ester CH₃COOC₂H₅ (ethyl acetate) with sodium ethoxide in ethanol, and then the subsequent reaction of compound A in the presence of acid. **Step 1: Identify the starting compound.** The starting compound is given as CH₃COOC₂H₅, which is ethyl acetate. **Step 2: Reaction with sodium ethoxide.** When ethyl acetate reacts with sodium ethoxide (C₂H₅ONa) in ethanol, it undergoes a condensation reaction. The sodium ethoxide acts as a base and deprotonates the hydrogen atom adjacent to the carbonyl group of the ester, leading to the formation of a β-keto ester. ...
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