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Among the following which one can have a...

Among the following which one can have a meso form?

A

a.`CH_(3)CH(OH)CH(Cl)C_(2)H_(5)`

B

b.`CH_(3)CH(OH)CH(OH)CH_(3)`

C

c.`C_(2)H_(5)CH(OH)CH(OH)CH_(3)`

D

d.`HOCH_(2)CH(Cl)CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound can have a meso form, we need to understand the concept of meso compounds. Meso compounds are those that have multiple stereocenters but possess an internal plane of symmetry, making them achiral. ### Step-by-Step Solution: 1. **Understand Meso Compounds**: - Meso compounds have multiple stereocenters and an internal plane of symmetry. This means that one half of the molecule is a mirror image of the other half. 2. **Analyze Each Option**: - We are given four options. We need to analyze each structure to check for the presence of an internal plane of symmetry. 3. **Option A**: - The structure has different groups attached to the stereocenters (e.g., CH3, C2H5, OH, CN). - When we try to draw a plane of symmetry, we find that CH3 does not match with C2H5, indicating no internal plane of symmetry. - **Conclusion**: Not a meso compound. 4. **Option B**: - The structure has CH3, OH, and hydrogen groups arranged such that there are two identical CH3 groups on either side. - When we draw a plane of symmetry, CH3 reflects onto CH3, OH reflects onto OH, and hydrogen reflects onto hydrogen. - **Conclusion**: This compound has an internal plane of symmetry, making it a meso compound. 5. **Option C**: - The structure has C2H5, OH, and CH3 groups. - The C2H5 group does not have a corresponding group on the other side to reflect onto, indicating no internal plane of symmetry. - **Conclusion**: Not a meso compound. 6. **Option D**: - The structure has OH, CH2, CH, and CH3 groups. - Similar to previous options, the groups do not match up across a potential plane of symmetry. - **Conclusion**: Not a meso compound. 7. **Final Conclusion**: - The only compound that has a meso form is **Option B**.

To determine which compound can have a meso form, we need to understand the concept of meso compounds. Meso compounds are those that have multiple stereocenters but possess an internal plane of symmetry, making them achiral. ### Step-by-Step Solution: 1. **Understand Meso Compounds**: - Meso compounds have multiple stereocenters and an internal plane of symmetry. This means that one half of the molecule is a mirror image of the other half. 2. **Analyze Each Option**: ...
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