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Assertion : Sb(2)S(3) is not soluble in ...

Assertion : `Sb_(2)S_(3)` is not soluble in yellow ammonium sulphide.
Reason : The common ion effect due to `S^(2)` ions reduces the solubility of `Sb_(2)S_(3)`

A

if both Assertion and Reason are true and reason is the correct explanation of the assertion.

B

if both assertion and reason are true but reason is not the correct expalanation of the assertion

C

if assertion is true, reason is false

D

both assertion and reason are false statements.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion:** - The assertion states that \( \text{Sb}_2\text{S}_3 \) is not soluble in yellow ammonium sulfide. - Yellow ammonium sulfide is a solution that contains \( \text{S}^{2-} \) ions. 2. **Solubility of \( \text{Sb}_2\text{S}_3 \):** - \( \text{Sb}_2\text{S}_3 \) (antimony sulfide) is known to have limited solubility in water but can dissolve in ammonium sulfide due to the formation of complex ions. - The reaction can be represented as: \[ \text{Sb}_2\text{S}_3 + 3 \text{NH}_4\text{S} \rightarrow 2 \text{NH}_4\text{SbS}_3 \] - This indicates that \( \text{Sb}_2\text{S}_3 \) is indeed soluble in ammonium sulfide. 3. **Understanding the Reason:** - The reason states that the common ion effect due to \( \text{S}^{2-} \) ions reduces the solubility of \( \text{Sb}_2\text{S}_3 \). - The common ion effect implies that the presence of a common ion (in this case, \( \text{S}^{2-} \)) in a solution will shift the equilibrium of a sparingly soluble salt to the left, thus reducing its solubility. - However, since \( \text{Sb}_2\text{S}_3 \) is soluble in ammonium sulfide, the presence of \( \text{S}^{2-} \) does not reduce its solubility in this context. 4. **Conclusion:** - Both the assertion and the reason are incorrect: - The assertion is false because \( \text{Sb}_2\text{S}_3 \) is soluble in yellow ammonium sulfide. - The reason is also false because the common ion effect does not apply in this case as \( \text{Sb}_2\text{S}_3 \) can dissolve in the presence of \( \text{S}^{2-} \). ### Final Answer: Both the assertion and the reason are false.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion:** - The assertion states that \( \text{Sb}_2\text{S}_3 \) is not soluble in yellow ammonium sulfide. - Yellow ammonium sulfide is a solution that contains \( \text{S}^{2-} \) ions. ...
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