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Assertion : Chloral reacts with phenyl c...

Assertion : Chloral reacts with phenyl chloride to form DDT.
Reason : It is an electrophilic substitution reaction.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reasonb is false

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the assertion and reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that chloral reacts with phenyl chloride to form DDT (Dichlorodiphenyltrichloroethane). - Chloral is represented as CCl3CHO, and phenyl chloride is chlorobenzene (C6H5Cl). 2. **Reaction Mechanism**: - When chloral (CCl3CHO) is heated with phenyl chloride (C6H5Cl) in the presence of a dehydrating agent like H2SO4, a reaction occurs. - The reaction involves the removal of water (H2O), which indicates that the process is not just a simple substitution but involves dehydration. 3. **Formation of DDT**: - The reaction leads to the formation of DDT, which has the structure of two benzene rings connected by a trichloroethane group. - The overall reaction can be summarized as: \[ 2 \text{C}_6\text{H}_5\text{Cl} + \text{CCl}_3\text{CHO} \xrightarrow{\text{H}_2\text{SO}_4} \text{DDT} + \text{H}_2\text{O} \] 4. **Understanding the Reason**: - The reason states that the reaction is an electrophilic substitution reaction. - However, since the reaction involves the removal of water, it is classified as a dehydration reaction, which is an elimination reaction rather than a substitution. 5. **Conclusion**: - The assertion is correct because chloral does react with phenyl chloride to form DDT. - The reason is incorrect because the reaction is not an electrophilic substitution reaction; it is a dehydration reaction. ### Final Answer: - The assertion is true, and the reason is false.

To solve the given question, we need to analyze the assertion and reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that chloral reacts with phenyl chloride to form DDT (Dichlorodiphenyltrichloroethane). - Chloral is represented as CCl3CHO, and phenyl chloride is chlorobenzene (C6H5Cl). ...
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