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C6H6underset(H2SO4)overset(HNO3)rarrXund...

`C_6H_6underset(H_2SO_4)overset(HNO_3)rarrXunderset(FeCl_3)overset(Cl_2)rarrY`
Sequence Y can be

A

3-nitrochlorobenzene

B

1-nitrochlorobenzene

C

4-nitrochlorobenzene

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions taking place and the products formed. ### Step 1: Identify the starting compound The starting compound is benzene, which has the molecular formula \( C_6H_6 \). ### Step 2: Nitration of Benzene When benzene is treated with a mixture of concentrated sulfuric acid (\( H_2SO_4 \)) and nitric acid (\( HNO_3 \)), a nitration reaction occurs. The nitric acid generates the nitronium ion (\( NO_2^+ \)), which acts as an electrophile. **Reaction:** \[ C_6H_6 + HNO_3 \xrightarrow{H_2SO_4} C_6H_5NO_2 + H_2O \] This reaction leads to the formation of nitrobenzene (\( C_6H_5NO_2 \)), which we will denote as product \( X \). ### Step 3: Chlorination of Nitrobenzene Next, nitrobenzene (\( X \)) is treated with chlorine (\( Cl_2 \)) in the presence of iron(III) chloride (\( FeCl_3 \)). This setup facilitates a chlorination reaction. **Key Concept:** The nitro group (\( NO_2 \)) is an electron-withdrawing group and directs incoming substituents to the meta position due to its deactivating effect on the benzene ring. **Reaction:** \[ C_6H_5NO_2 + Cl_2 \xrightarrow{FeCl_3} C_6H_4ClNO_2 \] Since the nitro group directs substitution to the meta position, the chlorine will be added to the meta position relative to the nitro group. ### Step 4: Identify the final product The final product \( Y \) will be 3-Nitrochlorobenzene, which can be represented as: \[ \text{3-Nitrochlorobenzene} \quad (C_6H_4ClNO_2) \] ### Conclusion The sequence \( Y \) can be identified as **3-Nitrochlorobenzene**.

To solve the problem step by step, we will analyze the reactions taking place and the products formed. ### Step 1: Identify the starting compound The starting compound is benzene, which has the molecular formula \( C_6H_6 \). ### Step 2: Nitration of Benzene When benzene is treated with a mixture of concentrated sulfuric acid (\( H_2SO_4 \)) and nitric acid (\( HNO_3 \)), a nitration reaction occurs. The nitric acid generates the nitronium ion (\( NO_2^+ \)), which acts as an electrophile. ...
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