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Assertion: Bleaching powder reacts with ...

Assertion: Bleaching powder reacts with dilure acids to evolve chlorine
Reason: The chlorine liberated by the action of dilute acids on bleaching powder is called avilable chlorine .

A

if both assertion and reason are true and reason is thr correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reson are false.

Text Solution

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The correct Answer is:
To solve the given assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Bleaching powder reacts with dilute acids to evolve chlorine." - **Chemical Reaction**: When bleaching powder (calcium hypochlorite, Ca(OCl)2) reacts with a dilute acid, such as hydrochloric acid (HCl) or sulfuric acid (H2SO4), it produces chlorine gas (Cl2). - **Example Reaction**: \[ \text{Ca(OCl)}_2 + 2 \text{HCl} \rightarrow \text{CaCl}_2 + 2 \text{H}_2\text{O} + \text{Cl}_2 \] - **Conclusion**: The assertion is true as bleaching powder does indeed react with dilute acids to release chlorine gas. ### Step 2: Analyze the Reason The reason states that "The chlorine liberated by the action of dilute acids on bleaching powder is called available chlorine." - **Definition of Available Chlorine**: Available chlorine refers to the amount of chlorine that can be released from a compound, such as bleaching powder, when it reacts. It is often expressed in terms of the percentage of chlorine that can be liberated from one mole of bleaching powder. - **Clarification**: When one mole of bleaching powder reacts with an acid, the chlorine released is termed as available chlorine, which is significant in understanding the bleaching action and disinfecting properties of the compound. - **Conclusion**: The reason is also true, as it accurately describes what available chlorine is. ### Step 3: Determine the Relationship - Both the assertion and reason are true statements. - However, the reason does not provide a correct explanation for the assertion. The assertion describes a chemical reaction, while the reason defines a term related to the product of that reaction. ### Final Conclusion - **Assertion**: True - **Reason**: True - **Explanation Relationship**: The reason is not the correct explanation of the assertion. ### Answer The correct answer is that both statements are true, but the reason is not the correct explanation of the assertion. ---

To solve the given assertion and reason question, we will analyze both statements step by step. ### Step 1: Analyze the Assertion The assertion states that "Bleaching powder reacts with dilute acids to evolve chlorine." - **Chemical Reaction**: When bleaching powder (calcium hypochlorite, Ca(OCl)2) reacts with a dilute acid, such as hydrochloric acid (HCl) or sulfuric acid (H2SO4), it produces chlorine gas (Cl2). - **Example Reaction**: \[ ...
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Bleaching power is a mixed salt of hydrochloric acid and hypochlorious acid. It has the formula, CaOCI_(2).H_(2)O . It is manuafactured by the action of chlorine on dry slaked lime at 40^(@)C . There is also a view that bleaching power is a mixture [Ca(OCI)_(2)+CaCI_(2).Ca(OH)_(2).H_(2)O] . The amount of chlorine obtained form a sample of bleching power by the treatement with excess of dilute acids or CO_(2) is called a available chlorine. A good sample of bleaching power constains 35-38% of available chlorine. On long standing, it undergoes auto-oxidation and the amount of acvailable chlorine decreases. The estimation of available chlorine is done volumetrically by (a) iodometric method or by (b) aresenite method. In textile industry, the cotton cloth is mainly bleached with the help of bleaching power. The chemical name of bleaching powder is