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Assertion : 2-Butanol on heating with H2...

Assertion : 2-Butanol on heating with `H_2SO_4` gives 1-butene and
2-butene
Reason: Dehydration of 2 - butanol follows Saytzeff's rule.

A

if both assertion and reason are true and reason is thr correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reson are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that 2-butanol on heating with sulfuric acid (H₂SO₄) produces 1-butene and 2-butene. - This is a dehydration reaction where an alcohol loses a water molecule to form an alkene. 2. **Dehydration of 2-Butanol**: - The structure of 2-butanol is CH₃-CH(OH)-CH₂-CH₃. - When heated with H₂SO₄, the hydroxyl group (OH) is removed along with a hydrogen atom from a neighboring carbon (beta carbon), resulting in the formation of alkenes. 3. **Applying Saytzeff's Rule**: - Saytzeff's rule states that in elimination reactions, the more substituted alkene (the one with more alkyl groups attached to the double bond) will be the major product. - In the case of 2-butanol, the dehydration can lead to two possible products: - 1-butene (less substituted, minor product) - 2-butene (more substituted, major product) 4. **Products Formation**: - The dehydration of 2-butanol can yield: - Major product: 2-butene (CH₃-CH=CH-CH₃) - Minor product: 1-butene (CH₂=CH-CH₂-CH₃) - Therefore, the assertion is correct. 5. **Analyzing the Reason**: - The reason states that the dehydration of 2-butanol follows Saytzeff's rule, which is indeed true as the formation of the more substituted alkene (2-butene) is favored. 6. **Conclusion**: - Both the assertion and reason are true, and the reason correctly explains the assertion. ### Final Answer: Both the assertion and reason are true, and the reason is the correct explanation of the assertion. ---

To solve the question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that 2-butanol on heating with sulfuric acid (H₂SO₄) produces 1-butene and 2-butene. - This is a dehydration reaction where an alcohol loses a water molecule to form an alkene. ...
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