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Assertion : cis -2- butene gives meso-2,...

Assertion : cis -2- butene gives meso-2, 3-butanediol with dilute
alkaline `KMnO_(4)` solution.
Reason : Dilute alkaline `KMnO_(4)` solution gives trans addition with alkenes.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that cis-2-butene gives meso-2,3-butanediol when treated with dilute alkaline KMnO4. - **Cis-2-butene Structure**: The structure of cis-2-butene can be represented as: ``` H3C H \ / C=C / \ H3C H ``` - When cis-2-butene undergoes oxidation with dilute alkaline KMnO4 (which is a syn-dihydroxylation reaction), it adds hydroxyl groups (OH) across the double bond. 2. **Reaction with Dilute Alkaline KMnO4**: - The reaction will yield: ``` H3C OH \ / C=C / \ OH H3C ``` - The product formed is 2,3-butanediol, and since it has a plane of symmetry, it is classified as a meso compound. 3. **Conclusion on Assertion**: - The assertion is **True** because cis-2-butene indeed gives meso-2,3-butanediol when treated with dilute alkaline KMnO4. 4. **Understanding the Reason**: - The reason states that dilute alkaline KMnO4 gives trans addition with alkenes. - However, this is incorrect because dilute alkaline KMnO4 actually leads to syn addition (cis addition) of hydroxyl groups across the double bond. 5. **Conclusion on Reason**: - The reason is **False** because it incorrectly describes the type of addition that occurs with dilute alkaline KMnO4. ### Final Answer: - Assertion: True - Reason: False

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that cis-2-butene gives meso-2,3-butanediol when treated with dilute alkaline KMnO4. - **Cis-2-butene Structure**: The structure of cis-2-butene can be represented as: ``` ...
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