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Assertion : HCOOH formic acid react wi...

Assertion : `HCOOH` formic acid react with `H_(2)SO_(4)` to form `CO`.
Reason : `H_(2)SO_(4)` is mild (moderate) oxidizing agent.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both asertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that formic acid (HCOOH) reacts with sulfuric acid (H₂SO₄) to form carbon monoxide (CO). **Reaction:** When formic acid is heated with concentrated sulfuric acid, it undergoes dehydration to produce carbon monoxide and water: \[ \text{HCOOH} + \text{H}_2\text{SO}_4 \rightarrow \text{CO} + \text{H}_2\text{O} \] Thus, the assertion is **true**. ### Step 2: Analyze the Reason The reason states that H₂SO₄ is a mild oxidizing agent. **Properties of H₂SO₄:** Concentrated sulfuric acid can act as a dehydrating agent and can also act as an oxidizing agent under certain conditions. However, in the case of the reaction with formic acid, H₂SO₄ primarily acts as a dehydrating agent, removing water from the reaction mixture rather than oxidizing formic acid. Thus, while it is true that H₂SO₄ can be a mild oxidizing agent, in this specific reaction, it is not acting as such. Therefore, the reason is **true**, but it does not correctly explain the assertion. ### Conclusion - The assertion is true. - The reason is true, but it is not the correct explanation for the assertion. ### Final Answer Both assertion and reason are true, but the reason is not a correct explanation of the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that formic acid (HCOOH) reacts with sulfuric acid (H₂SO₄) to form carbon monoxide (CO). **Reaction:** When formic acid is heated with concentrated sulfuric acid, it undergoes dehydration to produce carbon monoxide and water: \[ \text{HCOOH} + \text{H}_2\text{SO}_4 \rightarrow \text{CO} + \text{H}_2\text{O} \] ...
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