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In acidic medium which of the following ...

In acidic medium which of the following does not change its colour:

A

`MnO_(4)^(-)`

B

`MnO_(4)^(2-)`

C

`CrO_(4)^(2-)`

D

`FeO_(4)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options does not change its color in acidic medium, we will analyze the behavior of each compound when subjected to acidic conditions. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides several compounds, and we need to analyze their behavior in acidic medium. Let's denote the compounds as follows: - A: MnO4^- - B: MnO4^2- - C: CrO4^2- - D: FeO4^2- 2. **Analyze MnO4^- (Potassium Permanganate)**: - In acidic medium, MnO4^- (purple color) reacts as follows: \[ \text{MnO}_4^- + 8 \text{H}^+ + 5 \text{e}^- \rightarrow \text{Mn}^{2+} + 4 \text{H}_2\text{O} \] - The product, Mn^2+, is colorless. - **Conclusion**: MnO4^- changes from purple to colorless. 3. **Analyze MnO4^2- (Manganate Ion)**: - In acidic medium, MnO4^2- reacts as follows: \[ 2 \text{MnO}_4^{2-} + 2 \text{H}_2\text{O} \rightarrow 2 \text{MnO}_2 + 4 \text{OH}^- \] - MnO4^2- is dark green and converts to MnO2 which is brown. - **Conclusion**: MnO4^2- changes color. 4. **Analyze CrO4^2- (Chromate Ion)**: - In acidic medium, CrO4^2- reacts as follows: \[ 2 \text{CrO}_4^{2-} + 2 \text{H}^+ \rightarrow \text{Cr}_2\text{O}_7^{2-} + \text{H}_2\text{O} \] - CrO4^2- is yellow and converts to Cr2O7^2- which is orange. - **Conclusion**: CrO4^2- changes color. 5. **Analyze FeO4^2- (Ferrate Ion)**: - In acidic medium, FeO4^2- reacts as follows: \[ \text{FeO}_4^{2-} + 8 \text{H}^+ + 3 \text{e}^- \rightarrow \text{Fe}^{3+} + 4 \text{H}_2\text{O} \] - FeO4^2- is typically unstable and can appear in various colors, often pink or yellow. - **Conclusion**: FeO4^2- changes color. ### Final Conclusion: Among the options analyzed, **MnO4^-** is the only compound that does not change its color in acidic medium as it transitions from a colored state (purple) to a colorless state (Mn^2+). ### Answer: **Option A: MnO4^- does not change its color in acidic medium.**

To determine which of the given options does not change its color in acidic medium, we will analyze the behavior of each compound when subjected to acidic conditions. ### Step-by-Step Solution: 1. **Identify the Compounds**: The question provides several compounds, and we need to analyze their behavior in acidic medium. Let's denote the compounds as follows: - A: MnO4^- - B: MnO4^2- - C: CrO4^2- ...
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