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Assertion : Electrolysis of molten CaH2 ...

Assertion : Electrolysis of molten `CaH_2` produces hydrogen gas at anode.
Reason : In `CaH_2`, hydrogen is present in the form of hydride `H^(−)`.

A

Both Assertion and Reason are true and Reason is the correct explanation of Assertion

B

Both Assertion and Reason are true and Reason is not the correct explanation of Assertion

C

Assertion is true but Reason is false

D

Both Assertion and Reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Electrolysis of CaH₂**: - When molten calcium hydride (CaH₂) undergoes electrolysis, it dissociates into its constituent ions: \[ \text{CaH}_2 \rightarrow \text{Ca}^{2+} + 2\text{H}^{-} \] 2. **Identifying the Electrodes**: - In electrolysis, the cathode is the negatively charged electrode where reduction occurs, and the anode is the positively charged electrode where oxidation occurs. - The positively charged ion (\(\text{Ca}^{2+}\)) will migrate to the cathode, while the negatively charged ion (\(\text{H}^{-}\)) will migrate to the anode. 3. **Reactions at the Electrodes**: - **At the Cathode**: - The calcium ions (\(\text{Ca}^{2+}\)) will gain electrons (reduction) to form calcium metal: \[ \text{Ca}^{2+} + 2e^{-} \rightarrow \text{Ca} \] - **At the Anode**: - The hydride ions (\(\text{H}^{-}\)) will lose electrons (oxidation) to form hydrogen gas: \[ 2\text{H}^{-} \rightarrow \text{H}_2 + 2e^{-} \] 4. **Evaluating the Assertion**: - The assertion states that electrolysis of molten \(\text{CaH}_2\) produces hydrogen gas at the anode. Based on the reaction at the anode, this statement is true. 5. **Evaluating the Reason**: - The reason states that in \(\text{CaH}_2\), hydrogen is present in the form of hydride \(\text{H}^{-}\). This is also true, as the dissociation of \(\text{CaH}_2\) produces \(\text{H}^{-}\) ions. 6. **Conclusion**: - Both the assertion and the reason are true, and the reason correctly explains the assertion. Therefore, the correct answer is: - **Both assertion and reason are true. Reason is the correct explanation of assertion.** ### Final Answer: **Option A: Both assertion and reason are true. Reason is the correct explanation of assertion.** ---
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