Home
Class 12
CHEMISTRY
In the following reaction CH(3)CHO+NH(2)...

In the following reaction `CH_(3)CHO+NH_(2)*NH_(2)*toAoverset(B)toCH_(3)CH_(3)+N_(2)` Identify A and B .

A

`CH_(3)CH=N NH_(2)andC_(2)H_(5)ONa`

B

`CH_(3)CH_(2)-NH_(2)andC_(2)H_(5)ONa`

C

`CH_(3)-HN-NH-CH_(3)andC_(2)H_(5)OH`

D

`CH_(3)CH_(2)NH_(2)andC_(2)H_(5)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the products A and B in the reaction: \[ \text{CH}_3\text{CHO} + \text{NH}_2\text{NH}_2 \xrightarrow{B} \text{CH}_3\text{CH}_3 + \text{N}_2 \] ### Step-by-step Solution: 1. **Identify the Reactants**: - The reactants are acetaldehyde (CH₃CHO) and hydrazine (NH₂NH₂). 2. **Reaction of Acetaldehyde with Hydrazine**: - When acetaldehyde reacts with hydrazine, it forms a hydrazone. The reaction can be represented as: \[ \text{CH}_3\text{CHO} + \text{NH}_2\text{NH}_2 \rightarrow \text{CH}_3\text{C}(=N-NH_2)\text{H} \] - Here, A is the hydrazone product, which is CH₃C(=N-NH₂)H. 3. **Identify the Reaction Conditions**: - The product A (hydrazone) undergoes a reaction known as the Wolff-Kishner reduction. This requires a strong base (B) to convert the hydrazone into an alkane. 4. **Wolff-Kishner Reduction**: - The hydrazone reacts with a strong base (commonly sodium ethoxide, C₂H₅O⁻Na⁺) to eliminate nitrogen gas (N₂) and form the corresponding alkane (CH₃CH₃). - The reaction can be summarized as: \[ \text{CH}_3\text{C}(=N-NH_2)\text{H} \xrightarrow{B} \text{CH}_3\text{CH}_3 + \text{N}_2 \] 5. **Conclusion**: - Therefore, A is the hydrazone (CH₃C(=N-NH₂)H) and B is the strong base (C₂H₅O⁻Na⁺). ### Final Answer: - A = CH₃C(=N-NH₂)H (hydrazone) - B = C₂H₅O⁻Na⁺ (sodium ethoxide)
Promotional Banner

Similar Questions

Explore conceptually related problems

Write mechanism of the following reaction: CH_(3)CH_(2)OHoverset(HBr)toCH_(3)CH_(2)Br+H_(2)O .

(A)Write the mechanism of the following raction : CH_(3)CH_(2)OH overset(HBr) toCH_(3)CH_(2)Br+ H_(2)O (b) Write the equation involved in Reimer-Tiemann reaction.

Give the name of the following reaction: CH_(3)CHO+CH_(3)COCH_(3)overset(OH^(-))toCH_(3)CH(OH)CH_(2)COCH_(3)

Identify the product of following reaction : CH_(3)CHO+NH_(3)rarr

CH_(3)CH_(2)NH_(2) overset((CH_(3)CO)_(2))underset(Delta) to A+B , (A) and (B) are

CH_(3)CH_(2)NH_(2) overset((CH_(3)CO)_(2)O)underset(Delta) to A+B , (A) and (B) are

Identify the product of following reaction : CH_(3)CHO+HOCH_(2)CH_(2)OH rarr

CH_(3)CH_(2)NH_(2) is soluble in :-

The gases produced in the following reactions are respectively I: CH_(3)NH_(2) + NH_(2)Br to II: CH_(3)SO_(3)H + NaHCO_(3) to III: CH_(3) -underset(O)underset(||)C -NH_(2)+NaH to

Identify the product of following reaction : 2(CH_(3))_(2)CO+NH_(3)rarr