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Assertion (A) Gabriel phthalimide reacti...

Assertion (A) Gabriel phthalimide reaction can be used to prepare aryl and alkyl amines.
Reason (R ) Aryl halides have same reactivity as alkyl halides towards nucleophilic substitution reactions.

A

If both Assertion and Reason are true and Reason is correct explanation of Assertion.

B

If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

C

If Assertion is true but Reason is false.

D

If both Assertion and Reason and false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the Assertion (A) and Reason (R), we will analyze both statements step by step. ### Step 1: Understanding the Assertion **Assertion (A)**: Gabriel phthalimide reaction can be used to prepare aryl and alkyl amines. - The Gabriel phthalimide reaction is primarily used to synthesize primary amines from alkyl halides. - It involves the use of phthalimide, which is treated with a strong base (like KOH) to form a potassium phthalimide. This intermediate can then react with an alkyl halide to yield a substituted phthalimide. - Upon hydrolysis, this substituted phthalimide yields a primary amine. **Conclusion**: The assertion is **false** because the Gabriel phthalimide reaction is not used to prepare aryl amines; it is mainly used for alkyl amines. ### Step 2: Understanding the Reason **Reason (R)**: Aryl halides have the same reactivity as alkyl halides towards nucleophilic substitution reactions. - Aryl halides (halides attached to an aromatic ring) do not react in the same manner as alkyl halides in nucleophilic substitution reactions. - Aryl halides are generally less reactive due to the resonance stabilization of the aromatic ring, which makes the carbon-halogen bond stronger and less susceptible to nucleophilic attack. - In contrast, alkyl halides are more reactive towards nucleophilic substitution because they can undergo reactions more readily. **Conclusion**: The reason is **false** because aryl halides are less reactive than alkyl halides in nucleophilic substitution reactions. ### Final Conclusion Both the assertion and the reason are false. Therefore, the correct answer is that both statements are incorrect.
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