Home
Class 12
CHEMISTRY
In the given reaction CH(3)CH(2) CH = CH...

In the given reaction `CH_(3)CH_(2) CH = CHCH_(3) overset(X) to CH_(3)CH_(2)COOH +`
`CH_(3)COOH`
The X is

A

`C_(2)H_(5)ON a`

B

Conc. `HCl + "Anhy"ZnCl_(2)`

C

Anh. `AlCl_(3)`

D

`KMnO_(4)//OH^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction and identify the reagent \( X \), we will follow these steps: ### Step 1: Identify the Reactant The reactant is \( CH_3CH_2CH=CHCH_3 \), which is 2-pentene. This compound has a double bond between the second and third carbon atoms. ### Step 2: Understand the Reaction The reaction leads to the formation of two carboxylic acids: propanoic acid (\( CH_3CH_2COOH \)) and acetic acid (\( CH_3COOH \)). This indicates that the double bond in the alkene is undergoing oxidative cleavage. ### Step 3: Determine the Type of Reaction The reaction is an oxidative cleavage of the double bond. This type of reaction typically requires an oxidizing agent. ### Step 4: Identify Possible Reagents We need to identify which reagent can facilitate oxidative cleavage. The options provided are: 1. Sodium ethoxide 2. Concentrated HCl + Anhydrous zinc chloride 3. Anhydrous aluminum chloride 4. Potassium permanganate (\( KMnO_4 \)) in the presence of hydroxide ions (\( OH^- \)) ### Step 5: Analyze the Options - **Sodium ethoxide**: This acts as a base and does not facilitate oxidative cleavage. - **Concentrated HCl + Anhydrous zinc chloride**: This is a reagent used for different purposes, not for oxidative cleavage. - **Anhydrous aluminum chloride**: This is a Lewis acid and is not suitable for oxidative cleavage. - **Potassium permanganate (\( KMnO_4 \))**: This is a well-known oxidizing agent that can cleave double bonds oxidatively. ### Step 6: Confirm the Correct Reagent Using \( KMnO_4 \) in the presence of \( OH^- \) will lead to the formation of aldehydes first, followed by further oxidation to carboxylic acids. The reaction proceeds as follows: 1. The double bond is cleaved to form aldehydes. 2. The aldehydes are then oxidized to form the corresponding carboxylic acids. ### Conclusion Thus, the reagent \( X \) that facilitates the oxidative cleavage of the double bond in 2-pentene to yield propanoic acid and acetic acid is \( KMnO_4 \) in the presence of \( OH^- \). ### Final Answer The reagent \( X \) is \( KMnO_4 \) in \( OH^- \). ---

To solve the given reaction and identify the reagent \( X \), we will follow these steps: ### Step 1: Identify the Reactant The reactant is \( CH_3CH_2CH=CHCH_3 \), which is 2-pentene. This compound has a double bond between the second and third carbon atoms. ### Step 2: Understand the Reaction The reaction leads to the formation of two carboxylic acids: propanoic acid (\( CH_3CH_2COOH \)) and acetic acid (\( CH_3COOH \)). This indicates that the double bond in the alkene is undergoing oxidative cleavage. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

A chemist plans to prepare 1- bromo-2- pentene by the following reaction CH_(3)CH_(2)CH =CHCH_(3) + NBS overset(Delta)(to) CH_(3) CH_(2) CH= CHCH_(2)Br This plane is not likely to work because

The reaction CH_(2)=CH-CH_(3)+HBr rarr CH_(3)-overset(Br)overset(|)(C )HCH_(3) is

Consider the following reactions. I. CH_(2)=CHCOOH overset(Delta)to CH_(2)=CH_(2) II. III. CH_(3)CH(COOH)_(2) overset(Delta)to CH_(3)CH_(2)COOH In which cases, parent compound loses its functional group in preference?

CH_(3)(CH_(2))_(7)CH =CH(CH_(2))_(7).COOH is

Write the IUPAC name of CH_(3)CH_(2)CH=CH-COOH .

Why is CH_(2)=CH-COOH a stronger acid than CH_(3)CH_(2)COOH ?

Name the functional groups present in the following compounds. (a) CH_(3)COCH_(2)CH_(2)CH_(2)CH_(3) , (b) CH_(3)CH_(2)CH_(2)COOH (c ) CH_(3)CH_(2)CH_(2)CH_(2)CHO , (d) CH_(3)CH_(2)OH

In the given reaction: CH_(3)-CH_(2)-CH_(2)-O-CH_(2)-CH_(3) overset(HCl//Delta)rarr [X] +[Y] [X] and [Y] wil respectively be:

CH_(3)COOAgdarr+HNO_(3) to AgNO_(3)+CH_(3)COOH

CH_(3)COOAgdarr+HNO_(3) to AgNO_(3)+CH_(3)COOH