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Reaction of propanal with HCN followed b...

Reaction of propanal with HCN followed by acid hydrolysis of the reaction product with produce

A

propanoic acid

B

1-butylamine

C

`alpha`-hydroxybutanoic acid

D

all of the above

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of propanal with HCN followed by acid hydrolysis, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is propanal (CH3CH2CHO), which is an aldehyde. - The other reactant is hydrogen cyanide (HCN). 2. **Nucleophilic Addition Reaction**: - In the presence of HCN, the cyanide ion (CN⁻) acts as a nucleophile and attacks the carbonyl carbon of propanal. - The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{CHO} + \text{HCN} \rightarrow \text{CH}_3\text{CH}_2\text{C(OH)(CN)}\text{H} \] - This results in the formation of a cyanohydrin, specifically 2-cyanopropanol. 3. **Acid Hydrolysis**: - The next step involves the hydrolysis of the cyanohydrin in an acidic medium (H⁺ and H₂O). - The hydrolysis of the cyanohydrin leads to the formation of a carboxylic acid and the release of ammonia: \[ \text{CH}_3\text{CH}_2\text{C(OH)(CN)}\text{H} + H_2O \xrightarrow{H^+} \text{CH}_3\text{CH}_2\text{C(OH)(COOH)}\text{H} \] - This results in the formation of 2-hydroxybutanoic acid. 4. **Naming the Product**: - The product formed is 2-hydroxybutanoic acid, which can also be referred to as alpha-hydroxybutanoic acid because the hydroxyl group (-OH) is located at the second carbon (alpha position) of the butanoic acid chain. ### Final Product: The final product of the reaction of propanal with HCN followed by acid hydrolysis is **alpha-hydroxybutanoic acid**.

To solve the question regarding the reaction of propanal with HCN followed by acid hydrolysis, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is propanal (CH3CH2CHO), which is an aldehyde. - The other reactant is hydrogen cyanide (HCN). ...
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