Home
Class 12
CHEMISTRY
A Grignard reagent , such as (CH3MgBr) ...

A Grignard reagent , such as `(CH_3MgBr)` will react with `C_2H_5OH` and then with acidified water to produce

A

a secondary or tertiary alcohol

B

an aldehyde

C

a ketone

D

none of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of the Grignard reagent `(CH₃MgBr)` with `C₂H₅OH` followed by acidified water, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The Grignard reagent is `(CH₃MgBr)` and the alcohol is `C₂H₅OH`. 2. **Understand the Nature of Grignard Reagents**: Grignard reagents are strong nucleophiles and bases. They can react with electrophiles or abstract protons from acidic compounds. 3. **Reaction with Ethanol (C₂H₅OH)**: - When `(CH₃MgBr)` reacts with `C₂H₅OH`, it primarily acts as a base rather than a nucleophile because the product formed by nucleophilic attack would be unstable. - The Grignard reagent abstracts the acidic hydrogen from the hydroxyl group of ethanol. \[ \text{C₂H₅OH} + \text{CH₃MgBr} \rightarrow \text{C₂H₅O}^- + \text{CH₄} + \text{MgBr}^+ \] Here, methane `(CH₄)` is formed as a byproduct. 4. **Reaction with Acidified Water**: - The alkoxide ion `(C₂H₅O^-)` formed in the previous step will then react with acidified water (H⁺ from the acid). - This reaction will regenerate the alcohol: \[ \text{C₂H₅O}^- + \text{H}_2\text{O} \rightarrow \text{C₂H₅OH} + \text{OH}^- \] 5. **Final Products**: - The final products of the entire reaction sequence are methane `(CH₄)` and ethanol `(C₂H₅OH)`. However, since the question asks for the product after both reactions, we focus on the alkane produced. 6. **Conclusion**: The primary product of the reaction is methane `(CH₄)`, and since the question asks what is produced after both reactions, the answer is **none of the above** if the options provided do not include methane. ### Final Answer: The reaction produces **methane (CH₄)** and the answer to the question is **none of the above**.

To solve the question regarding the reaction of the Grignard reagent `(CH₃MgBr)` with `C₂H₅OH` followed by acidified water, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: The Grignard reagent is `(CH₃MgBr)` and the alcohol is `C₂H₅OH`. 2. **Understand the Nature of Grignard Reagents**: Grignard reagents are strong nucleophiles and bases. They can react with electrophiles or abstract protons from acidic compounds. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

In the reaction C_(2)H_(5) MgBr +

A compound [A] has the formula C_(4)H_(8)O_(2) . When reacted with a Grignard reagent, CH_(3)MgBr , it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent. The compound [A] is

A compound [A] has the formula C_(4)H_(8)O_(2) . When reacted with a Grignard reagent, CH_(3)MgBr , it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent. The alcohol [B] is

A compound [A] has the formula C_(4)H_(8)O_(2) . When reacted with a Grignard reagent, CH_(3)MgBr , it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent. The compound [A] is

How does acetaldehyde react with: C_(2)H_(5)MgBr

Two different Grignard reagents (X) and (Y ) produce C_(6)H_(5)CH_(2)C(CH_(3))_(2)OH on reaction with (P) and (Q) respectively. Give the structure of (X),(Y),(P) and (Q).

CH_(3)OH , CH_(4), NaOH , C_(2)H_(5)OH

CH_(3)OH , CH_(4), NaOH , C_(2)H_(5)OH