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Acetaldehyde , in the presence of NaOH, ...

Acetaldehyde , in the presence of NaOH, will

A

produce 3-hydroxybutanal

B

be converted to acetic acid

C

produce ethyl acetate

D

do none of the above

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of acetaldehyde in the presence of NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants:** - The reactant is acetaldehyde, which has the chemical formula CH₃CHO. 2. **Understand the Role of NaOH:** - Sodium hydroxide (NaOH) is a strong base. In this reaction, it will act to deprotonate the alpha hydrogen of acetaldehyde. 3. **Deprotonation:** - The alpha carbon (the carbon adjacent to the carbonyl group) of acetaldehyde has hydrogens that can be abstracted by the base. When NaOH abstracts a hydrogen from the alpha carbon, it forms an enolate ion: \[ \text{CH}_3C(=O)H \rightarrow \text{CH}_2C(=O)H^- \] 4. **Nucleophilic Attack:** - The enolate ion (CH₂C(=O)H⁻) will then act as a nucleophile and attack the carbonyl carbon of another acetaldehyde molecule. This forms a new carbon-carbon bond: \[ \text{CH}_2C(=O)H^- + \text{CH}_3CHO \rightarrow \text{CH}_3C(OH)(CH_2CHO) \] 5. **Formation of 3-Hydroxybutanal:** - The product formed is 3-hydroxybutanal (or 3-hydroxybutyraldehyde), which can also be referred to as 3-hydroxybutanol when considering its alcohol character. The structure can be represented as: \[ \text{CH}_3CHOHCH_2CHO \] 6. **Determine the Correct Answer:** - Among the given options, the correct answer is that acetaldehyde in the presence of NaOH will produce 3-hydroxybutanol. ### Conclusion: The correct answer is **Option 1: Produce 3-hydroxybutanol**.

To solve the question regarding the reaction of acetaldehyde in the presence of NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants:** - The reactant is acetaldehyde, which has the chemical formula CH₃CHO. 2. **Understand the Role of NaOH:** ...
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Knowledge Check

  • The reaction of acetaldehyde in the presence of Al(OC_2H_5)_3 produces :

    A
    `CH_3CH(OH)CH_2CHO`
    B
    `CH_3CH = CH - CHO`
    C
    `CH_3COOC_2H_5`
    D
    No reaction
  • Acetaldehyde cannot give:

    A
    Iodoform test
    B
    Lucas test
    C
    Benedict test
    D
    Tollen's test
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