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Assertion: Cyclobutane is less stable th...

Assertion: Cyclobutane is less stable than cyclopentane
Reason : The bond angles in cyclobutane and cyclopentane are `90^@` and `108^@`, respectively

A

Both Assertion and Reason are true and Reason is the correct explanation of Assertion

B

Both Assertion and Reason are true but Reason is not a correct explanation of Assertion

C

Assertion is true but Reason is false

D

Assertion is false but Reason is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Cyclobutane is less stable than cyclopentane." - **Explanation**: Cyclobutane is a four-membered ring, while cyclopentane is a five-membered ring. Generally, larger rings tend to be more stable due to less angle strain. ### Step 2: Understand the Reason The reason states that "The bond angles in cyclobutane and cyclopentane are 90° and 108°, respectively." - **Explanation**: The bond angle in cyclobutane is 90°, which is significantly less than the ideal tetrahedral angle of 109.5°. This creates angle strain. In contrast, cyclopentane has a bond angle of 108°, which is closer to the ideal angle and thus experiences less angle strain. ### Step 3: Analyze the Relationship Now, we need to connect the assertion and the reason. - **Analysis**: The lower bond angle in cyclobutane (90°) leads to greater internal strain compared to the bond angle in cyclopentane (108°). This internal strain is inversely related to stability; therefore, cyclobutane, having a higher internal strain, is less stable than cyclopentane. ### Step 4: Conclusion Both the assertion and reason are true, and the reason correctly explains the assertion. ### Final Answer Both the assertion and reason are true, and the reason is the correct explanation of the assertion. ---

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Cyclobutane is less stable than cyclopentane." - **Explanation**: Cyclobutane is a four-membered ring, while cyclopentane is a five-membered ring. Generally, larger rings tend to be more stable due to less angle strain. ### Step 2: Understand the Reason ...
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