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Assertion: Bromoacetic acid reacts with ...

Assertion: Bromoacetic acid reacts with conc. NaOH to form `alpha`-ethoxy acetic acid.
Reason: It is `S_(N)1` mechanism.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reson are true but reason is not the correct explanation of assertion.

C

if assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that bromoacetic acid reacts with concentrated NaOH to form alpha-ethoxy acetic acid. 1. **Identify bromoacetic acid**: The structure of bromoacetic acid is BrCH2COOH. 2. **Reaction with NaOH**: When bromoacetic acid reacts with concentrated NaOH, an acid-base reaction occurs. The hydroxide ion (OH-) from NaOH will react with the acidic hydrogen (H) of the carboxylic acid (COOH) group. 3. **Formation of salt**: The reaction will lead to the formation of sodium bromoacetate (BrCH2COONa) and water (H2O). Thus, the assertion that bromoacetic acid forms alpha-ethoxy acetic acid is incorrect. The product is sodium bromoacetate, not alpha-ethoxy acetic acid. ### Step 2: Analyze the Reason The reason states that the reaction occurs via an SN1 mechanism. 1. **Understanding SN1 mechanism**: The SN1 mechanism involves the formation of a carbocation intermediate and is typically seen in reactions where a good leaving group is present and the substrate can stabilize the carbocation. 2. **Nature of the reaction**: In the case of bromoacetic acid reacting with NaOH, there is no nucleophilic substitution occurring. Instead, it is an acid-base reaction leading to salt formation. Therefore, the reaction does not follow an SN1 mechanism. ### Conclusion Both the assertion and the reason are false. The assertion incorrectly states the product, and the reason incorrectly describes the mechanism. ### Final Answer Both the assertion and reason are false.
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