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The correct relation is...

The correct relation is

A

`DeltaG-RT" ln "K//Q`

B

`DeltaG=-RT" ln "K`

C

`DeltaG=-RT" ln "Q//K`

D

`DeltaG=+RT" ln "Q`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the correct relation involving Gibbs free energy change (ΔG), we will follow these steps: ### Step-by-Step Solution: 1. **Understanding Gibbs Free Energy Change**: - The Gibbs free energy change (ΔG) indicates the spontaneity of a reaction. If ΔG is negative, the reaction is spontaneous; if positive, it is non-spontaneous. 2. **Standard Gibbs Free Energy Change**: - The standard Gibbs free energy change (ΔG°) is defined for reactions under standard conditions (1 bar pressure, 1 M concentration). It can be calculated using the formula: \[ \Delta G° = -RT \ln K \] where \( R \) is the universal gas constant, \( T \) is the temperature in Kelvin, and \( K \) is the equilibrium constant. 3. **Gibbs Free Energy Change for Non-Standard Conditions**: - For reactions that are not at equilibrium, the Gibbs free energy change is given by: \[ \Delta G = \Delta G° + RT \ln Q \] where \( Q \) is the reaction quotient, which reflects the current concentrations of reactants and products. 4. **Combining the Equations**: - We can substitute the expression for ΔG° into the equation for ΔG: \[ \Delta G = -RT \ln K + RT \ln Q \] - This can be rearranged to: \[ \Delta G = RT (\ln Q - \ln K) = RT \ln \left(\frac{Q}{K}\right) \] 5. **Identifying the Correct Relation**: - From the derived equation, we see that ΔG is related to the ratio of the reaction quotient to the equilibrium constant: \[ \Delta G = RT \ln \left(\frac{Q}{K}\right) \] - Therefore, the correct relation among the given options is likely to be the one that matches this derived equation. ### Conclusion: - Based on the analysis, the correct answer is **Option C**, which corresponds to the relation we derived.

To solve the question regarding the correct relation involving Gibbs free energy change (ΔG), we will follow these steps: ### Step-by-Step Solution: 1. **Understanding Gibbs Free Energy Change**: - The Gibbs free energy change (ΔG) indicates the spontaneity of a reaction. If ΔG is negative, the reaction is spontaneous; if positive, it is non-spontaneous. 2. **Standard Gibbs Free Energy Change**: ...
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