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Assertion : NH3 is liquidities more easi...

Assertion : NH3 is liquidities more easily than `CO_(2)`.
Reason : Critical temperature of NH3 is more than `CO_(2)`.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is the currect explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason provided. **Assertion:** NH3 is liquefied more easily than CO2. **Reason:** The critical temperature of NH3 is more than that of CO2. ### Step-by-Step Solution: 1. **Understanding Liquefaction:** - Liquefaction refers to the process of a substance transitioning from a gas to a liquid state. The ease of liquefaction is influenced by intermolecular forces and the critical temperature of the substance. 2. **Defining Critical Temperature:** - The critical temperature (T_c) of a substance is the temperature above which it cannot exist as a liquid, regardless of the pressure applied. A higher critical temperature indicates that a substance can be liquefied more easily. 3. **Comparing NH3 and CO2:** - Ammonia (NH3) has strong hydrogen bonding due to the presence of nitrogen and hydrogen. This results in stronger intermolecular forces. - Carbon dioxide (CO2), on the other hand, has weaker van der Waals forces and does not exhibit hydrogen bonding. 4. **Critical Temperatures:** - The critical temperature of NH3 is approximately 132°C, while that of CO2 is around 31°C. Since the critical temperature of NH3 is higher than that of CO2, NH3 can be liquefied at higher temperatures and pressures compared to CO2. 5. **Conclusion:** - Since NH3 has a higher critical temperature than CO2, it can be liquefied more easily. Therefore, both the assertion and reason are correct, and the reason correctly explains the assertion. ### Final Answer: Both the assertion and reason are correct, and the reason is the correct explanation for the assertion.
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