Home
Class 12
CHEMISTRY
Out of BeF(2), MgF(2), CaF(2), SrF(2) wh...

Out of `BeF_(2), MgF_(2), CaF_(2), SrF_(2)` which has maximum solubility :

A

`BeF_(2)`

B

`MgF_(2)`

C

`CaF_(2)`

D

`SrF_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the compounds \( \text{BeF}_2, \text{MgF}_2, \text{CaF}_2, \text{SrF}_2 \) has the maximum solubility, we need to consider the factors that affect solubility, particularly hydration enthalpy. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds in question are \( \text{BeF}_2 \), \( \text{MgF}_2 \), \( \text{CaF}_2 \), and \( \text{SrF}_2 \). These are fluorides of group 2 elements (alkaline earth metals). 2. **Understand Hydration Enthalpy**: Hydration enthalpy is the energy released when ions are surrounded by water molecules. A higher hydration enthalpy generally indicates greater solubility because it means that more energy is released when the ions dissolve in water. 3. **Compare the Sizes of Cations**: The size of the cations increases as we move down the group from beryllium to strontium: - \( \text{Be}^{2+} \) is smaller than \( \text{Mg}^{2+} \), which is smaller than \( \text{Ca}^{2+} \), which is smaller than \( \text{Sr}^{2+} \). 4. **Relate Size to Hydration Enthalpy**: Smaller cations have a higher charge density, which leads to stronger interactions with water molecules. Therefore, \( \text{Be}^{2+} \) will have the highest hydration enthalpy due to its small size. 5. **Evaluate Solubility**: - \( \text{BeF}_2 \) has a high hydration enthalpy due to the small size of \( \text{Be}^{2+} \), making it highly soluble. - In contrast, \( \text{MgF}_2 \), \( \text{CaF}_2 \), and \( \text{SrF}_2 \) have larger cations, resulting in lower hydration enthalpy and thus lower solubility. These compounds are generally considered to be almost insoluble in water. 6. **Conclusion**: Based on the above analysis, \( \text{BeF}_2 \) has the maximum solubility among the given compounds. ### Final Answer: The compound with maximum solubility is \( \text{BeF}_2 \).

To determine which of the compounds \( \text{BeF}_2, \text{MgF}_2, \text{CaF}_2, \text{SrF}_2 \) has the maximum solubility, we need to consider the factors that affect solubility, particularly hydration enthalpy. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds in question are \( \text{BeF}_2 \), \( \text{MgF}_2 \), \( \text{CaF}_2 \), and \( \text{SrF}_2 \). These are fluorides of group 2 elements (alkaline earth metals). 2. **Understand Hydration Enthalpy**: Hydration enthalpy is the energy released when ions are surrounded by water molecules. A higher hydration enthalpy generally indicates greater solubility because it means that more energy is released when the ions dissolve in water. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

In which solvent KBr has maximum solubility?

In which solvent NaCl has maximum solubility ?

Which one has maximum solubility in liquid C Cl_(4) ?

Molecular shape of XeF_(2), BeF_(2) and CF_(2) are :

Lattice enthalpies of BeF_(2),MgF_(2),CaF_(2) and BaF_(2) are -2906,-2610,-2459 and -2367 kJ mol^(-1) resoectively. Hydration enthalpies of Be^(2+),Ca^(2+),Ba^(2+) and F^(Θ) are -2194,-1921,-1577,-130 and -457 kJ mol^(-1) respectively. Which of the fluorides has the highest solublility in water?

Ca(OH)_(2)+2FH to CaF_(2)darr+2H_(2)O

Ca(OH)_(2)+2FH to CaF_(2)darr+2H_(2)O

Which of the following sulphides has maximum solubility in water?

Solubility product constant K_(sp) of salts of types MX, MX_(2) and M_(3)X at temperature ‘T’ are 4.0xx10^(-8), 3.2xx10^(-14) , and 2.7xx10^(-15) respectively. Which salt has maximum solubility.