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Assertion : Tert. Butyl amine can be for...

Assertion : Tert. Butyl amine can be formed by Gabriel phthalimide synthesis
Reason : It follow `S_(N)1` mechanism

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Tert. Butyl amine can be formed by Gabriel phthalimide synthesis." - **Analysis**: The Gabriel phthalimide synthesis is primarily used for the preparation of primary amines. It involves the reaction of phthalimide with a suitable alkyl halide in the presence of a strong base. Tertiary butyl amine (tert-butyl amine) is a tertiary amine, which cannot be synthesized using this method because the Gabriel synthesis does not yield tertiary amines. ### Step 2: Understand the Reason The reason states that "It follows SN1 mechanism." - **Analysis**: The Gabriel phthalimide synthesis actually follows an SN2 mechanism, not SN1. In SN2 reactions, the nucleophile attacks the electrophile in a single concerted step, which is characteristic of the mechanism used in Gabriel synthesis. Therefore, this statement is also incorrect. ### Step 3: Conclusion Both the assertion and the reason are false. The assertion is false because tert-butyl amine cannot be formed by Gabriel phthalimide synthesis, and the reason is false because the mechanism involved is SN2, not SN1. ### Final Answer Both the assertion and the reason are false. ---
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