MnO is :

A

Ferromagnetic

B

Antiferromagnetic

C

Ferrimagnetic

D

Dimagnetic

Text Solution

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The correct Answer is:
To determine the magnetic nature of MnO, we will go through the following steps: ### Step 1: Identify the oxidation state of manganese in MnO - Manganese (Mn) has an atomic number of 25. In MnO, manganese is in the +2 oxidation state (Mn²⁺), as oxygen (O) typically has a -2 oxidation state. ### Step 2: Determine the electron configuration of Mn²⁺ - The electron configuration of neutral manganese (Mn) is [Ar] 4s² 3d⁵. - When manganese loses two electrons to form Mn²⁺, it loses the two 4s electrons first, resulting in the configuration [Ar] 3d⁵. ### Step 3: Analyze the d-electron configuration - The 3d⁵ configuration indicates that there are 5 electrons in the d subshell. This is a half-filled d subshell, which is known to have certain magnetic properties. ### Step 4: Determine the presence of unpaired electrons - In a half-filled d subshell (3d⁵), all five d electrons are unpaired. This results in a net magnetic moment. ### Step 5: Classify the magnetic behavior - Since MnO has unpaired electrons, it exhibits paramagnetic behavior. However, we need to consider the crystal structure and interactions in the solid state. - In the case of MnO, the magnetic interactions between the Mn²⁺ ions lead to antiferromagnetic ordering. ### Step 6: Conclusion - Therefore, MnO is classified as antiferromagnetic due to the alignment of the spins of the unpaired electrons in opposite directions, resulting in a cancellation of their magnetic moments. ### Final Answer MnO is **antiferromagnetic**. ---
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