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A graph plot between x/m and pressure T...

A graph plot between `x/m` and pressure The value of n at point A is

A

2

B

1

C

`1/2`

D

'1/3'

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the value of \( n \) at point A on the graph plotting \( \frac{x}{m} \) against pressure, we will follow these steps: ### Step-by-Step Solution: 1. **Understand the Freundlich Adsorption Isotherm**: The Freundlich adsorption isotherm is given by the equation: \[ \frac{x}{m} = kP^{\frac{1}{n}} \] where: - \( \frac{x}{m} \) is the amount of adsorbate per unit mass of adsorbent, - \( P \) is the pressure, - \( k \) is a constant, - \( n \) is a constant that indicates the nature of the adsorption. 2. **Analyze the Graph**: The graph plots \( \frac{x}{m} \) (on the y-axis) against pressure \( P \) (on the x-axis). The behavior of the graph at different pressure ranges is crucial: - At low pressures, \( \frac{x}{m} \) is directly proportional to \( P \) (linear relationship), which implies \( n = 1 \). - At high pressures, \( \frac{x}{m} \) approaches a constant value, indicating \( n \) tends to infinity (adsorption becomes independent of pressure). - At intermediate pressures, the relationship is non-linear, and \( n \) is greater than 1. 3. **Identify Point A**: Since point A is described as being at intermediate pressure, we can conclude that it does not fall into the low or high-pressure categories. 4. **Determine the Value of \( n \)**: Given that point A is at an intermediate pressure, we can conclude that: \[ n > 1 \] 5. **Final Conclusion**: Therefore, the value of \( n \) at point A is greater than 1. ### Summary: The value of \( n \) at point A is greater than 1.
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