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Which of the following is incorrect abou...

Which of the following is incorrect about `K_(2)Cr_(2)O_(7)` ?

A

It can be prepared from `K_(2)CrO_(4)`.

B

It is used in redox titrations.

C

It is stable in both acid & base.

D

It is orange in colour

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement about potassium dichromate (K₂Cr₂O₇) is incorrect, we will analyze each option provided. ### Step 1: Analyze Option A **Statement:** It can be prepared from K₂CrO₄ (potassium chromate). **Analysis:** This statement is correct. Potassium dichromate can indeed be prepared from potassium chromate by reacting it with sulfuric acid (H₂SO₄). The reaction is as follows: \[ \text{K}_2\text{CrO}_4 + \text{H}_2\text{SO}_4 \rightarrow \text{K}_2\text{Cr}_2\text{O}_7 + \text{K}_2\text{SO}_4 + \text{H}_2\text{O} \] Thus, Option A is correct. ### Step 2: Analyze Option B **Statement:** It is used in redox titration. **Analysis:** This statement is also correct. Potassium dichromate is commonly used as a powerful oxidizing agent in redox titrations, particularly in acidic medium. For example, it can oxidize ferrous ions (Fe²⁺) to ferric ions (Fe³⁺) while itself being reduced. Therefore, Option B is correct. ### Step 3: Analyze Option C **Statement:** It is stable in both acid and base. **Analysis:** This statement is incorrect. The dichromate ion (\( \text{Cr}_2\text{O}_7^{2-} \)) is stable in acidic conditions. However, in basic conditions, it converts to the chromate ion (\( \text{CrO}_4^{2-} \)). Therefore, it is not stable in both acidic and basic media. Thus, Option C is incorrect. ### Step 4: Analyze Option D **Statement:** It is orange in color. **Analysis:** This statement is correct. Potassium dichromate is known for its distinctive orange color. Therefore, Option D is correct. ### Conclusion The incorrect statement about potassium dichromate (K₂Cr₂O₇) is **Option C**: "It is stable in both acid and base." ---

To determine which statement about potassium dichromate (K₂Cr₂O₇) is incorrect, we will analyze each option provided. ### Step 1: Analyze Option A **Statement:** It can be prepared from K₂CrO₄ (potassium chromate). **Analysis:** This statement is correct. Potassium dichromate can indeed be prepared from potassium chromate by reacting it with sulfuric acid (H₂SO₄). The reaction is as follows: \[ \text{K}_2\text{CrO}_4 + \text{H}_2\text{SO}_4 \rightarrow \text{K}_2\text{Cr}_2\text{O}_7 + \text{K}_2\text{SO}_4 + \text{H}_2\text{O} \] Thus, Option A is correct. ...
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