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Discuss the effect of catalyst on the activation energy.

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Arrhenius studies the effect of temperature on the rate of a reaction and postulted that rate constant varies with temperature exponentially as k=Ae^(E_(a)//RT) . Thuis method is generally used for finding the activation energy of a reaction. Keeping temperature constant, the effect of catalyst on the activation energy has also been studied. If the rate of reaction doubles for 10^(@)C rise of temperature form 290K to 300K, the activation energy of the reaction will be approximately :

Arrhenius studies the effect of temperature on the rate of a reaction and postulted that rate constant varies with temperature exponentially as k=Ae^(E_(a)//RT) . Thuis method is generally used for finding the activation energy of a reaction. Keeping temperature constant, the effect of catalyst on the activation energy has also been studied. If x is the fraction of molecules having energy greater than E_(a) it will be given by :

Arrhenius studies the effect of temperature on the rate of a reaction and postulted that rate constant varies with temperature exponentially as k=Ae^(E_(a)//RT) . Thuis method is generally used for finding the activation energy of a reaction. Keeping temperature constant, the effect of catalyst on the activation energy has also been studied. The pre-exponetial factor in the Arrhenius equation of a first order reaction has the unit :

Activation energy is:

The graph of the effect of catalyst on activation energy is given below. Fill up the blanks X and Y with appropriate statements

At 227^(@)C , the presence of catalyst causes the activation energy of a reaction to decrease by 4.606 K cal. The rate of the reaction will be increased by : -

What is the effect of adding a catalyst on (a) Activation energy (Ea), and (b) Gibbs energy ( DeltaG ) of a reaction?

The activation energy of a first order reaction at 300 K is 60 kJ mol^(-1) . In the presence of a catalyst, the activation energy gets lowered to 50kJ mol^(-1) at 300 K . How many times the reaction rate change in the presence of a catalyst at the same temperature ?

What is activation energy ?

A negative catalyst ......... the activation energy.

ICSE-CHEMICAL KINETICS-EXERCISE (PART- II (DESCRIPTIVE QUESRTIONS) B. SHORT ANSWER QUESTIONS )
  1. Comment on the following statements. A reaction with a higher activ...

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  2. Comment on the following statements. CH4 does not react with oxygen...

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  3. Discuss the effect of catalyst on the activation energy.

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  4. What is activation energy? How is the rate constant of a reaction rela...

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  5. What is an activated complex ? Explain with the help of a suitable exa...

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  6. Define the terms: Instantaneous rate of a reaction

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  7. Define the terms: Average rate of reaction

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  8. Define the terms: Half-life period and reaction life time.

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  9. What is meant by rate of reaction ? Show that the rate of reaction can...

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  10. How is the rate of reaction expressed ? Write the factors which affect...

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  11. Explain the terms rate equation and specific reaction rate.

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  12. What is meant by molecularity of a reaction ? Why the molecularity of ...

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  13. What is the difference between rate law and law of mass action?

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  14. What is meant by order of a reaction ?

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  15. Differentiate between order and molecularity of a reaction.

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  16. Derive the integrated rate equation for first order reactions.

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  17. Write the name of any two methods to determine the order of a reaction...

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  18. How the order of a reaction can be determined by integral equation met...

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  19. The kinetics of a reaction, A + 2B to C + D obey the rate equation : ...

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  20. The kinetics of a reaction, A + 2B to C + D obey the rate equation : ...

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