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What is activation energy? How is the ra...

What is activation energy? How is the rate constant of a reaction related to its activation energy ?

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Can a reaction have negative activation energy?

Activation energy of the reaction is :

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The rate of reaction increases with increase in activation energy.

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A colliison between reactant molecules must occur with a certain minimum energy before it is effective in yielding Product molecules. This minimum energy is called activation energy E_(a) Large the value of activation energy, smaller the value of rate constant k . Larger is the value of activation energy, greater is the effect of temperature rise on rate constant k . E_(f) = Activation energy of forward reaction E_(b) = Activation energy of backward reaction Delta H = E_(f) - E_(b) E_(f) = threshold energy The rate constant of a certain reaction is given by k = Ae^(-E_(a)//RT) (where A = Arrhenius constant). Which factor should be lowered so that the rate of reaction may increase?

A colliison between reactant molecules must occur with a certain minimum energy before it is effective in yielding Product molecules. This minimum energy is called activation energy E_(a) Large the value of activation energy, smaller the value of rate constant k . Larger is the value of activation energy, greater is the effect of temperature rise on rate constant k . E_(f) = Activation energy of forward reaction E_(b) = Activation energy of backward reaction Delta H = E_(f) - E_(b) E_(f) = threshold energy The activation eneries for forward and backward reactions in a chemical reaction are 30.5 and 45.4 kJ mol^(-1) respectively. The reaction is

A colliison between reactant molecules must occur with a certain minimum energy before it is effective in yielding Product molecules. This minimum energy is called activation energy E_(a) Large the value of activation energy, smaller the value of rate constant k . Larger is the value of activation energy, greater is the effect of temperature rise on rate constant k . E_(f) = Activation energy of forward reaction E_(b) = Activation energy of backward reaction Delta H = E_(f) - E_(b) E_(f) = threshold energy If a reaction A + B rarr C is exothermic to the extent 30 kJ mol^(-1) and the forward reaction has an activation energy of 249 kJ mol^(-1) the activation energy for reverse reaction in kJ mol^(-1) is

A colliison between reactant molecules must occur with a certain minimum energy before it is effective in yielding Product molecules. This minimum energy is called activation energy E_(a) Large the value of activation energy, smaller the value of rate constant k . Larger is the value of activation energy, greater is the effect of temperature rise on rate constant k . E_(f) = Activation energy of forward reaction E_(b) = Activation energy of backward reaction Delta H = E_(f) - E_(b) E_(f) = threshold energy For two reactions, activation energies are E_(a1) and E_(a2) , rate constant are k_(1) and k_(2) at the same temperature. If k_(1) gt k_(2) , then

ICSE-CHEMICAL KINETICS-EXERCISE (PART- II (DESCRIPTIVE QUESRTIONS) B. SHORT ANSWER QUESTIONS )
  1. Comment on the following statements. CH4 does not react with oxygen...

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  2. Discuss the effect of catalyst on the activation energy.

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  3. What is activation energy? How is the rate constant of a reaction rela...

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  4. What is an activated complex ? Explain with the help of a suitable exa...

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  5. Define the terms: Instantaneous rate of a reaction

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  6. Define the terms: Average rate of reaction

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  7. Define the terms: Half-life period and reaction life time.

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  8. What is meant by rate of reaction ? Show that the rate of reaction can...

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  9. How is the rate of reaction expressed ? Write the factors which affect...

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  10. Explain the terms rate equation and specific reaction rate.

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  11. What is meant by molecularity of a reaction ? Why the molecularity of ...

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  12. What is the difference between rate law and law of mass action?

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  13. What is meant by order of a reaction ?

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  14. Differentiate between order and molecularity of a reaction.

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  15. Derive the integrated rate equation for first order reactions.

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  16. Write the name of any two methods to determine the order of a reaction...

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  17. How the order of a reaction can be determined by integral equation met...

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  18. The kinetics of a reaction, A + 2B to C + D obey the rate equation : ...

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  19. The kinetics of a reaction, A + 2B to C + D obey the rate equation : ...

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  20. The kinetics of a reaction, A + 2B to C + D obey the rate equation : ...

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