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In the following reaction product 'P' is...

In the following reaction product 'P' is
`R-overset(O)overset(||)C-Clunderset(BaSO_(4))overset(H_(2))toP`.

A

`RCH_(2)OH`

B

`RCOOH`

C

`RCHO`

D

`RCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the product 'P' formed in the reaction of R-C(=O)Cl with H2 in the presence of BaSO4, we can follow these steps: ### Step 1: Identify the Reactants The reactant in the reaction is an acid chloride, which can be represented as R-C(=O)Cl. Here, R represents an alkyl or aryl group. **Hint:** Recognize that acid chlorides are derivatives of carboxylic acids and are reactive due to the presence of the chlorine atom. ### Step 2: Understand the Reaction Conditions The reaction is carried out in the presence of hydrogen gas (H2) and a catalyst, which is palladium on barium sulfate (Pd/BaSO4). This combination indicates that the reaction is likely a Rosenmund reduction. **Hint:** The Rosenmund reduction specifically involves the reduction of acid chlorides to aldehydes using hydrogen gas and a palladium catalyst. ### Step 3: Predict the Reaction Outcome In the Rosenmund reduction, the chlorine atom in the acid chloride (R-C(=O)Cl) is replaced by a hydrogen atom, resulting in the formation of an aldehyde (R-CHO). **Hint:** Remember that the chlorine atom is replaced by hydrogen during the reduction process, leading to the formation of an aldehyde. ### Step 4: Write the Product The product 'P' formed from the reaction of R-C(=O)Cl with H2 in the presence of Pd/BaSO4 is R-CHO, which is the general formula for an aldehyde. **Hint:** Aldehydes have the functional group -CHO, which is characteristic of their structure. ### Step 5: Identify the By-Product Along with the formation of the aldehyde, hydrogen chloride (HCl) is produced as a by-product of the reaction. **Hint:** Always consider the by-products formed during chemical reactions, especially when halogens are involved. ### Conclusion The product 'P' in the given reaction is R-CHO, which is an aldehyde. ### Final Answer The correct answer is that the product 'P' is an aldehyde, represented as R-CHO. ---
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