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The correct order of increasing acidic s...

The correct order of increasing acidic strength is

A

Phenol`lt`Ethanol`lt`Chloroacetic acid`lt` Acetic acid

B

Ethanol`lt`Phenol`lt`Chloroacetic acid`lt` Acetic acid

C

Ethanol`lt`Phenol`lt`Acetic acid`lt` Chloroacetic acid

D

Chloroacetic acid`lt`Acetic acid`lt` Phenol `lt` Ethanol

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The correct Answer is:
To determine the correct order of increasing acidic strength among the given compounds, we will analyze the stability of the anions formed when these acids donate a proton (H⁺). The more stable the anion, the stronger the acid. ### Step-by-Step Solution: 1. **Identify the Compounds**: We have four compounds to compare: - Ethanol (C₂H₅OH) - Phenol (C₆H₅OH) - Chloroacetic acid (ClCH₂COOH) - Acetic acid (CH₃COOH) 2. **Write the Anions**: When these acids donate a proton (H⁺), they form the following anions: - Ethanol → O⁻ (alkoxide ion) - Phenol → C₆H₅O⁻ (phenoxide ion) - Chloroacetic acid → ClCH₂COO⁻ (chloroacetate ion) - Acetic acid → CH₃COO⁻ (acetate ion) 3. **Analyze Anion Stability**: - **Ethanol (O⁻)**: The alkoxide ion is not stabilized by resonance, making it less stable. - **Phenol (C₆H₅O⁻)**: The phenoxide ion can participate in resonance with the benzene ring, which stabilizes it somewhat, but it is not as stable as the anions of carboxylic acids. - **Chloroacetic acid (ClCH₂COO⁻)**: The chloroacetate ion benefits from resonance and the -I (inductive) effect of the chlorine atom, which withdraws electron density and stabilizes the negative charge. - **Acetic acid (CH₃COO⁻)**: The acetate ion also has resonance stabilization, but lacks the additional stabilizing effect provided by the chlorine in chloroacetic acid. 4. **Rank the Acids**: Based on the stability of the anions: - Least stable (and thus weakest acid): Ethanol (O⁻) - Next: Phenol (C₆H₅O⁻) - Next: Acetic acid (CH₃COO⁻) - Most stable (and thus strongest acid): Chloroacetic acid (ClCH₂COO⁻) 5. **Final Order**: The correct order of increasing acidic strength is: **Ethanol < Phenol < Acetic Acid < Chloroacetic Acid**

To determine the correct order of increasing acidic strength among the given compounds, we will analyze the stability of the anions formed when these acids donate a proton (H⁺). The more stable the anion, the stronger the acid. ### Step-by-Step Solution: 1. **Identify the Compounds**: We have four compounds to compare: - Ethanol (C₂H₅OH) - Phenol (C₆H₅OH) ...
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ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. The boiling point of acetic acid is higher than expected from its mole...

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  2. Acetic acid is a weak acid because

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  3. The correct order of increasing acidic strength is

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  4. Compound Ph-O-overset(O)overset(||)C-Ph can be prepared by the reacti...

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  5. Carboxylic group shows acidic character because

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  6. The Hell-Volhard-Zelinsky reaction is used to

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  7. When chlorine is passed through acetic acid in presence of halogen car...

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  8. Acetic acid exists as dimer in benzene due to

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  9. Weakest acid among the following is

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  10. Ester formation involves the reaction of

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  11. Which of the following reaction is expected to readily give a hydrocar...

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  12. Heating a mixture of sodium benzoate and soda-lime gives

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  13. Which of the following compounds will react with NaHCO(3) solution to ...

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  14. Chlorination of toluene in presence of light and heat followed by trea...

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  15. Which of the following carboxylic acid undergoes decarboxylation easil...

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  16. CH(3)CH(2)COOHunderset("Red P")overset(Br(2))tooverset(NH(3))toY Y i...

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  17. When propionic acid is treated with aqueous sodium bicarbonate, CO(2) ...

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  18. Addition of water to alkynes occurs in acidic medium and in the presen...

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  19. Which of the following compounds is most reactive towards nucleophilic...

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  20. The reagent which does not react with both, acetophenone and benzaldeh...

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