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Compound Ph-O-overset(O)overset(||)C-Ph ...

Compound `Ph-O-overset(O)overset(||)C-Ph` can be prepared by the reaction of

A

Phenol and benzoic acid in the presence of NaOH

B

Phenol and benzoyl chloride in the presence of pyridine

C

Phenol and benzoyl chloride in the presence of `ZnCl_(2)`

D

Phenol and benzaldehyde in the presence of palladium.

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The correct Answer is:
To prepare the compound `Ph-O-C(=O)-Ph`, which is an ester, we can follow these steps: ### Step 1: Identify the Reactants The compound consists of a phenyl group (Ph) attached to an oxygen atom, which is then connected to a carbonyl group (C=O) and another phenyl group. This indicates that the compound is an ester formed from phenol and benzoic acid. ### Step 2: Write the Reaction The reaction involves the esterification process between phenol (C6H5OH) and benzoic acid (C6H5COOH). The general reaction for ester formation can be represented as: \[ \text{Phenol} + \text{Benzoic Acid} \rightarrow \text{Ester} + \text{Water} \] ### Step 3: Mechanism of Esterification 1. **Protonation of the Alcohol**: In an acidic medium, the hydroxyl group of phenol can be protonated to form a better leaving group. 2. **Nucleophilic Attack**: The phenol (now protonated) acts as a nucleophile and attacks the carbonyl carbon of benzoic acid. 3. **Formation of Tetrahedral Intermediate**: This leads to the formation of a tetrahedral intermediate. 4. **Elimination of Water**: The tetrahedral intermediate collapses, leading to the elimination of water and the formation of the ester. ### Step 4: Final Product The final product of this reaction is the ester `Ph-O-C(=O)-Ph` (phenyl benzoate) along with the release of water. ### Conclusion Thus, the compound `Ph-O-C(=O)-Ph` can be prepared by the reaction of phenol and benzoic acid in the presence of an acidic medium or basic medium. ---
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Treatement of compound Ph-O-overset(O)overset(||)(C)-Ph with NaOH solution yields

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CH_(3)CH_(2)-underset(Ph)underset(|)overset(OH)overset(|)C-CH_(3) cannnot be prepared by:

Ph-overset(O)overset(||)(C)-CH_(3)+underset("(excess)")(CH_(2)=O) overset(OH^(Theta))toPh-overset(O)overset(||)(C)-C(CH_(2)OH)_(3) In the above reaction how times of aldol reaction takes place ?

Write the systematic IUPAC names of the following compounds : H-overset(O) overset(||) C-overset(O ) overset(||) C - H

ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE (PART-I OBJECTIVE QUESTIONS)
  1. Acetic acid is a weak acid because

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  2. The correct order of increasing acidic strength is

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  3. Compound Ph-O-overset(O)overset(||)C-Ph can be prepared by the reacti...

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  4. Carboxylic group shows acidic character because

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  5. The Hell-Volhard-Zelinsky reaction is used to

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  6. When chlorine is passed through acetic acid in presence of halogen car...

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  7. Acetic acid exists as dimer in benzene due to

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  8. Weakest acid among the following is

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  9. Ester formation involves the reaction of

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  10. Which of the following reaction is expected to readily give a hydrocar...

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  11. Heating a mixture of sodium benzoate and soda-lime gives

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  12. Which of the following compounds will react with NaHCO(3) solution to ...

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  13. Chlorination of toluene in presence of light and heat followed by trea...

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  14. Which of the following carboxylic acid undergoes decarboxylation easil...

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  15. CH(3)CH(2)COOHunderset("Red P")overset(Br(2))tooverset(NH(3))toY Y i...

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  16. When propionic acid is treated with aqueous sodium bicarbonate, CO(2) ...

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  17. Addition of water to alkynes occurs in acidic medium and in the presen...

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  18. Which of the following compounds is most reactive towards nucleophilic...

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  19. The reagent which does not react with both, acetophenone and benzaldeh...

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  20. Cannizaro's reaction is not given by

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