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Compounds A and C in the following react...

Compounds A and C in the following reaction are
`CH_(3)CHOunderset((ii)H_(2)O)overset((i)CH_(3)MgBr)toAoverset(H_(2)SO_(4).Delta)to(B)overset("Hydroboration oxidation")to(C)`

A

identical

B

positional isomers

C

functional isomers

D

optical isomers.

Text Solution

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The correct Answer is:
To solve the question regarding the compounds A and C in the given reaction, we will break down the steps involved in the transformation of the compounds. ### Step 1: Identify the starting compound The starting compound is **acetaldehyde** (CH₃CHO). This is the first reactant in the reaction. ### Step 2: Reaction with Grignard Reagent The Grignard reagent used is **methylmagnesium bromide (CH₃MgBr)**. In this reaction, the nucleophilic methyl group (CH₃⁻) from the Grignard reagent attacks the carbonyl carbon of acetaldehyde. This results in the formation of a **secondary alcohol**. - **Reaction**: \[ \text{CH}_3\text{CHO} + \text{CH}_3\text{MgBr} \rightarrow \text{A} \quad (\text{where A is CH}_3\text{CH(OH)CH}_3) \] ### Step 3: Formation of Compound A After the reaction with the Grignard reagent, we obtain **compound A**, which is **2-butanol (CH₃CH(OH)CH₃)**. ### Step 4: Dehydration of Compound A Next, compound A reacts with **sulfuric acid (H₂SO₄)** upon heating. The sulfuric acid protonates the alcohol group, converting it into a better leaving group (water). This leads to the elimination of water and the formation of an **alkene**. - **Reaction**: \[ \text{A} \xrightarrow{\text{H}_2\text{SO}_4, \Delta} \text{B} \quad (\text{where B is butene}) \] ### Step 5: Hydroboration-Oxidation of Compound B The alkene (compound B) undergoes **hydroboration-oxidation**. This reaction involves the addition of borane (BH₃) followed by oxidation with hydrogen peroxide (H₂O₂) in a basic medium. The reaction follows the **anti-Markovnikov rule**, resulting in the formation of an alcohol. - **Reaction**: \[ \text{B} \xrightarrow{\text{BH}_3/\text{H}_2\text{O}_2} \text{C} \quad (\text{where C is butanol, CH}_3\text{CH}_2\text{CH}_2\text{OH}) \] ### Step 6: Identify Compound C After hydroboration-oxidation, we obtain **compound C**, which is **1-butanol (CH₃CH₂CH₂OH)**. ### Conclusion In summary, we have: - **Compound A**: 2-butanol (CH₃CH(OH)CH₃) - **Compound C**: 1-butanol (CH₃CH₂CH₂OH) The relationship between compounds A and C is that they are **positional isomers**; they have the same molecular formula but differ in the position of the hydroxyl (-OH) group.

To solve the question regarding the compounds A and C in the given reaction, we will break down the steps involved in the transformation of the compounds. ### Step 1: Identify the starting compound The starting compound is **acetaldehyde** (CH₃CHO). This is the first reactant in the reaction. ### Step 2: Reaction with Grignard Reagent The Grignard reagent used is **methylmagnesium bromide (CH₃MgBr)**. In this reaction, the nucleophilic methyl group (CH₃⁻) from the Grignard reagent attacks the carbonyl carbon of acetaldehyde. This results in the formation of a **secondary alcohol**. ...
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Compounds (A) and (C ) in the following reactions are CH_(3)CHO overset((i)CH_(3)MgBr)underset((ii)H_(2)O)to(A) overset(H_(2)SO_(4),Delta)to(B)overset("Hydroboration oxidation")to (C)

Complete the following reaction : CH_(3)CHOoverset(CH_(3)MgBr)to_____overset(H_(3)O+)to___

Complete the following reactions CH_(3)CH=CH_(2)overset(mCPBA)rarr A overset(C_(2)H_(5)MgBr)underset(H_(3)O^(+))rarr B

Ph-CH=CH-CHO overset((i) CH_(3)CH_(2)MgBr)to overset((ii) H_(3)O^(o+))to(X) overset(Cu,Delta)to(Y)

Complete the following reaction sequence : CH_(3)-overset(O)overset(||)C-CH_(3)overset((i)CH_(3)MgBr)underset((ii)H_(2)O)rarr(A)overset("Na metal")underset("ether")rarr(B)overset(CH_(3)-Br)rarr(C)

Complete the following reaction sequence : CH_(3)-overset(O)overset(||)C-CH_(3)overset((i)CH_(3)MgBr)underset((ii)H_(2)O)rarr(A)overset("Na metal")underset("ether")rarr(B)overset(CH_(3)-Br)rarr(C)

CH_(3)CH_(2)OHunderset(443 K)overset(H_(2)SO_(4)(conc.))to[A]overset(H_(2)O //H^(+))to[B]overset(PCI_(5))to[C]

The IUPAC name of the following compound is: H_(3)C-overset(CH_(3))overset(|)CH-overset(OH)overset(|)CH-CH_(2)-COOH

Give the structures of A, B and C in the following: CH_(3)CHOunderset(H_(2)SO_(4))overset(K_(2)Cr_(2)O_(7))toAoverset(PCl_(5))toBunderset(AlCl_(3))overset(C_(6)H_(6))toC

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