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Why Grignard reagents are not used in pl...

Why Grignard reagents are not used in place of dialkyl cadmium during the preparation of ketones from acid chlorides ?

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### Step-by-Step Solution: 1. **Understanding the Reactants**: - We start with an acid chloride (RCOCl) and want to prepare a ketone. The common reagents for this transformation are dialkyl cadmium (R2Cd) and Grignard reagents (RMgX). 2. **Role of Dialkyl Cadmium**: - When dialkyl cadmium is used, it reacts with the acid chloride to form a ketone (R-C(=O)-R'). The reaction proceeds smoothly without any side reactions, as cadmium does not react further with the ketone product. ...
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ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE (PART-II DESCRIPTIVE QUESTIONS) (VERY SHORT QUESTIONS)
  1. Why is there no compound such as ethanone?

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  2. Do aliphatic aldehydes show position isomerism?

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  3. Why Grignard reagents are not used in place of dialkyl cadmium during ...

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  4. How is acetone obtained from ethanol?

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  5. Complete the following reaction : C(6)H(6)+RCOClunderset("(Anhy.)")o...

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  6. Write the chemical reaction for getting 2-propanol from ethanal.

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  7. Why ketones do not easily unergo oxidation?

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  8. Ethanal undergoes aldol condensation but trichloroethanal does not.

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  9. Benzaldehyde and formaldehyde do not undergo condensation on treatment...

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  10. How will you distinguish between acetone and ethyl alcohol?

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  11. Which of the following compounds is used in the preservation of biolog...

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  12. What are the following: Fehling's solution

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  13. What are the following: Tollens' reagent

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  14. What are the following: Baeyer's reagent

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  15. What are the following: Baeyer's reagent

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  16. Write the chemical name and structure of Rochelle salt.

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  17. What type of reactions are given by the carbonyl group in aldehydes an...

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  18. Name two methods commonly used to convert a carbonyl (gtC=O) group int...

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  19. What type of aldehydes and ketones undergo aldol condensation?

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  20. What type of aldehydes undergo Cannizzaro's reaction?

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