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Calcium acetate on heating gives which ...

Calcium acetate on heating gives ___ which gives__ on heating with iodine and sodium hydroxide solution.

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A compound (X) with the molecular formula C_6 H_10 O_4 is a neutral liquid. On heating (X) , under reflux with aqueous sodium hydroxide and distilling the product. A colourless liquid is obtained which on warming with iodine and aqueous sodium hydroxide gives a pale yellow precipatate (Y) . The residue in the distilling flask is the sodium salt of an acid (Z) , which decolourises aqueous acidified potassium permaganate (VII) on heating. Identify (X), (Y) , and (Z) and give all the reactions involved.

Salts P, Q,R,S,T,U and V undergo reactions (i) to (vii) respectively. Identify the cation present in these salts on the basis of these reactions. Tabulate your answer in the formate given below. (i) When the salt Pis heated with sodium hydroxide solution a vigorous reaction takes place and a colourless gas is evolved with a pungent and suffocating smell that brings tears in our eyes. The evolved gas gives dense white fumes with a moist glass rod depped with hydrochloric acid. (ii) Addition of sodium hydroxide solution to a solution of salt Q gives a thick white precipitae which is soluble in excess of sodium hydroxide solution to form a clear solution. (iii) Addition of ammonium hydroxide solution to a solution of salt R gives a dark blue precipitate which is soluble is excess of ammonium hydroxide solution to form an intense deep blue solution. (iv) Addition of ammonium hydroxide solution to a solution of 5 gives a dirty green [bottle green] precipitate which is insoluble even in the excess of ammonium hydroxide solution. (v) Addition of ammonium hydroxide solution to a solution of T gives a reddish brown (rust precipitate] precipitate which is insoluble even in the excess of ammonium hydroxide solution. (vi) Addition of ammonium hydroxide solution to a solution of V gives a geletaneous white precipitate which is soluble in excess of ammonium hydroxide solution to form a clear solution. (vii) Addition of ammonium hydroxide solution to a solution of V gives no precipitate but it gives a chalky white precipitate with sodium hydroxide solution which is insoluble even in the excess of sodium hydroxide solution.

Which of the following disproportionate (s) in heating with sodium hydroxide?

ICSE-ISC QUESTION PAPER-PART-II(SECTION-B)
  1. Calcium acetate on heating gives which gives on heating with iodine a...

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  2. Write the formula of the following compounds : Potassium trioxalato...

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  3. Write the formula of the following compounds : Hexaaquairon (II) su...

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  4. Name the types of isomerism shown by the following pairs of compounds ...

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  5. The anhydride of nitric acid is:

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  6. For the coordination complex ion [Co(NH(3))(6)]^(3+) Give the IUPAC ...

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  7. For the coordination complex ion [Co(NH(3))(6)]^(3+). What is the o...

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  8. For the complex ion of [Co(NH3)6]^(3+) State the hybridization of th...

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  9. For the complex ion of [Co(NH3)6]^(3+) : State the magnetic nature ...

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  10. Give balanced equations for the following reactions : Potassium per...

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  11. Give balanced equations for the following reactions : Lead sulphide...

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  12. Give balanced equations for the following reactions : Ozone is trea...

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  13. Write all the chemical reactions involved in the manufacture of sulphu...

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  14. (i) What are the types of hybridization of iodine in interhalogen comp...

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  15. Draw the structure of xenon hexaluoride (XeF6) molecule and state the ...

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  16. Give the equations for the conversion of argentite (Ag2S) to metallic ...

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  17. How can the following conversions be brought about : Acetaldehyde t...

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  18. How can the following conversions be brought about : Nitrobenzene t...

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  19. How can the following conversions be brought about : Acetic acid t...

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  20. How can the following conversions be brought about : Aniline to ben...

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  21. How will you distinguish between primary, secondary and tertiary amine...

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