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Darzen's process....

Darzen's process.

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This method is used for the preparation of alkyl chloride by treating alcohols with thionyl chloride.
`underset("Alcohol")(ROH)+underset("Thionyl chloride")(SOCl_(2))overset(Delta)(to)underset("Alkyl chloride")(RCl)+SO_(2)+HCl`
This is the best method for the proparation of pure alkyl chlorides because the other two products (`SO_(2)` HCl) being gases, leave the reaction mixture.
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Knowledge Check

  • Which reaction is termed as Darzen's reaction ?

    A
    ROH + HCI
    B
    `ROH + PCI_(5)`
    C
    `ROH+SOCl_(2)`
    D
    `ROH+PCl_(3)`
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