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Which of the following compounds will un...

Which of the following compounds will undergo aldol condensation, which the Cannizzaro reaction and which neither ? Write the structures of the expected products of aldol condensation and Cannizzaro reaction.
2,2-Dimethylbutanal.

Text Solution

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2-dimethylbutanal do not contain `alpha`-hydrogen. Hence, these undergo Cannizzaro.s reaction. The reactions and the structures of the expected products are given below :
`underset("2-2-Dimethylbutanal")( CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CHO)overset("Conc. NaOH")tounderset("2,2-Dimethylbutanal-1-ol")(CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)OH)+underset("Sod. 2, 2-dimethylbutanoate")(CH_(3)CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-COONa)`
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ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-EXERCISE (PART-II DESCRIPTIVE QUESTIONS) ( LONG ANSWER QUESTIONS)
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  10. How does formaldehyde react with : CH(3)MgBr

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  12. How does formaldehyde react with : Fehling's solution

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  17. How does acetaldehyde react with: Chlorine

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  18. How does acetaldehyde react with: NaHSO(3)

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  19. How does acetaldehyde react with: 2,4-dinitrophenylhydrazine.

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