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Acetaldehyde on treatment with hydrogen ...

Acetaldehyde on treatment with hydrogen cyanide followed by hydrolysis gives:

A

formic acid

B

acetic acid

C

lactic acid

D

tartaric acid

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The correct Answer is:
To solve the question of what acetaldehyde produces when treated with hydrogen cyanide followed by hydrolysis, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is acetaldehyde, which has the chemical formula CH₃CHO. 2. **Reaction with Hydrogen Cyanide**: - When acetaldehyde reacts with hydrogen cyanide (HCN), it undergoes a nucleophilic addition reaction. The cyanide ion (CN⁻) acts as a nucleophile and attacks the carbonyl carbon of acetaldehyde. - This reaction produces a cyanohydrin. The structure of the cyanohydrin formed is CH₃CHOHCN, which can be written as CH₃C(OH)(CN)H. 3. **Hydrolysis of the Cyanohydrin**: - The cyanohydrin formed can undergo hydrolysis when treated with water in the presence of an acid (like dilute HCl). - During hydrolysis, the cyanohydrin will convert into a carboxylic acid and ammonia. The hydroxyl group (OH) and the carboxyl group (COOH) will be formed from the hydrolysis of the cyanide group (CN). 4. **Formation of Lactic Acid**: - The hydrolysis of the cyanohydrin leads to the formation of lactic acid (C₃H₆O₃). The reaction can be summarized as: - CH₃C(OH)(CN)H + H₂O → CH₃C(OH)(COOH) + NH₄⁺ - The product formed is lactic acid, which has the structure CH₃C(OH)(COOH). 5. **Conclusion**: - Therefore, when acetaldehyde is treated with hydrogen cyanide followed by hydrolysis, the final product is lactic acid. ### Final Answer: The correct answer is **lactic acid (Option 3)**. ---
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ICSE-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-ISC EXAMINATION QUESTIONS (PART-I OBJECTIVE QUESTIONS) (MULTIPLE CHOICE QUESTION)
  1. Benzaldehyde, when heated with an alcoholic solution of potassium cyan...

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  2. When acetic acid is reacted with calcium hydroxide and the product is ...

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  3. When acetaldehyde is treated with Grignard reagent, followed by hydrol...

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  4. In the equation CH(3)COOH+Cl(2)+underset(-HCl)overset("red P")toA. T...

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  5. Formic acid is prepared by heating oxalic acid with

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  6. Acetaldehyde on treatment with hydrogen cyanide followed by hydrolysis...

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  7. Effervescence takes place when sodium carbonate solution is added to

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  8. The compound which gives a positive haloform test and a positive Fehli...

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  9. Benzaldehyde, when heated with an alcoholic solution of potassium cyan...

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  10. When acetic acid is reacted with calcium hydroxide and the product is ...

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  11. When acetaldehyde is treated with Grignard reagent, followed by hydrol...

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  12. In the equation CH(3)COOH+Cl(2)+underset(-HCl)overset("red P")toA. T...

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  13. Formic acid is prepared by heating oxalic acid with

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  14. Acetaldehyde on treatment with hydrogen cyanide followed by hydrolysis...

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  15. Effervescence takes place when sodium carbonate solution is added to

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  16. The compound which gives a positive haloform test and a positive Fehli...

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  17. Benzaldehyde, when heated with an alcoholic solution of potassium cyan...

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  18. When acetic acid is reacted with calcium hydroxide and the product is ...

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  19. When acetaldehyde is treated with Grignard reagent, followed by hydrol...

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  20. In the equation CH(3)COOH+Cl(2)overset("RedP")underset(-HCl)rarrA, the...

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