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The compound which gives a positive halo...

The compound which gives a positive haloform test and a positive Fehling solution test is :

A

acetone

B

acetaldehyde

C

formaldehyde

D

diethyl ether

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which compound gives a positive haloform test and a positive Fehling's solution test, we can follow these steps: ### Step 1: Understanding the Tests - **Haloform Test**: This test is used to identify methyl ketones (or aldehydes with an alpha-methyl group). A positive result indicates the presence of a methyl group adjacent to the carbonyl group. - **Fehling's Test**: This test is used to detect aldehydes. A positive result is indicated by the reduction of the deep blue copper(II) solution to a red precipitate of copper(I) oxide. ### Step 2: Analyzing the Options 1. **Acetone (CH3COCH3)**: This is a ketone and does have a methyl group adjacent to the carbonyl. It would give a positive haloform test but does not give a positive Fehling's test since it is a ketone. 2. **Acetaldehyde (CH3CHO)**: This is an aldehyde and has an alpha-methyl group. It will give a positive haloform test due to the presence of the methyl group adjacent to the carbonyl. It will also give a positive Fehling's test because it is an aldehyde. 3. **Formaldehyde (HCHO)**: This is also an aldehyde but does not have an alpha-methyl group. It will give a positive Fehling's test but not a haloform test. 4. **Diethyl Ether (C2H5)2O**: This is an ether and does not contain a carbonyl group. It will not give either test. ### Step 3: Conclusion Based on the analysis: - **Acetaldehyde (CH3CHO)** is the only compound that gives both a positive haloform test and a positive Fehling's test. Thus, the answer is **Acetaldehyde**. ---
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