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Consider the following: (i) 2H2O((I))to ...

Consider the following: (i) `2H_2O_((I))to O_(2(g))+4H_((aq))^++4e^-` , `E_(cell)^@=+1.23` V
(ii) `2SO_(4(aq))^(2-)to S_2O_(8(aq))^(2-)+2e^(-)` , `E_(cell)^@=+1.96` V
Which of the following statements is true?

A

In the electrolysis of dil. `H_2SO_4` , (i) is preferred at the anode.

B

In the electrolysis of conc. `H_2SO_4` (1) is preferred at the anode.

C

In the electrolysis of dil. `H_2SO_4` , (ii) is preferred at the anode.

D

In the electrolysis of conc. `H_2SO_4` , both (i) and (ii) occur at anode.

Text Solution

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The correct Answer is:
A

In the electrolysis of dil. `H_2SO_4` , (i) is preferred at the anode.
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