Home
Class 12
CHEMISTRY
A hypothetical reaction, A2 + B2rarr2AB ...

A hypothetical reaction, `A_2 + B_2rarr2AB` follows the following mechanism:
`A_2hArrA+A` …...............fast
`A+B_2rarrAB+B` …..........slow
`A+B `rarr` AB .................fast
The order of the overall reaction is

A

2

B

`3//2`

C

1

D

0

Text Solution

Verified by Experts

The correct Answer is:
B

Rate =k[A] [`B_2`]
But K=`([A]^2)/([A_2])` or [A] = `sqrt(K.[A_2])`
Rate =`k.sqrt(K)sqrt([A_2][B_2])=k.[A_2]^(1//2)[B_2]`
Order =`1+1/2=3//2`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    MTG GUIDE|Exercise CHECK YOUR NEET VITALS|25 Videos
  • CHEMICAL KINETICS

    MTG GUIDE|Exercise AIPMT/NEET (MCQs)|22 Videos
  • CHEMICAL KINETICS

    MTG GUIDE|Exercise AIPMT/NEET (MCQs)|22 Videos
  • BIOMOLECULES

    MTG GUIDE|Exercise AIPMT/NEET (MCQS)|19 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    MTG GUIDE|Exercise AIPMT/NEET |9 Videos

Similar Questions

Explore conceptually related problems

The hypothetical gaseous reaction A+B to AB

For reaction, 2B+A rarr 2C Which of the following is correct ?

A reaction A_(2)+B_(2)rarr 2AB occurs by the following mechanism: Ararr A+A … (slow) A+B_(2)rarr AB+B … (fast) A+Brarr AB … (fast) Its order would be

A hypothetical reaction A_(2) + B_(2) rarr 2AB follows the mechanism as given below: A_(2) hArr A+A ("fast") A+B_(2) rarr AB+B (slow) A+B rarr AB (fast) The order of the overall reaction is

In a reaction 2A + B rarr A_(2)B , the reactant A will disappear at

In hypothetical reaction, A_(2)+B_(2)rarr2AB , follows the follows the mechnism as given below : {:(A_(2)hArrA+A,("fast reaction")),(A+B_(2)rarrAB+B,("slow reaction")),(A+BrarrAB,("fast reaction")):} Give the rate law and order of reaction

MTG GUIDE-CHEMICAL KINETICS-TOPICWISE PRACTICE QUESTIONS
  1. For the first order decomposition reaction of N2O5,it is observed that...

    Text Solution

    |

  2. Nitrogen tetraoxide (N204) decomposes as : N2O(4(g))rarr2NO(2(g)) ...

    Text Solution

    |

  3. A hypothetical reaction, A2 + B2rarr2AB follows the following mechanis...

    Text Solution

    |

  4. The rate law for reaction hetween the substances A and B is given by R...

    Text Solution

    |

  5. The rate law for the reaction , RCl+NaOH((aq))rarrROH+NaClis given b...

    Text Solution

    |

  6. The rate of the reaction, N(2(g)) + 3H(2(g)) rarr 2NH(3(g)), was measu...

    Text Solution

    |

  7. Which of the following statements is incorrect?

    Text Solution

    |

  8. The rate expression for the reaction, A((g)) +B((g)) rarr C((g)), is r...

    Text Solution

    |

  9. For the reaction : H(2(g)) + Br(2(g)) rarr 2HBr((g)), the experimental...

    Text Solution

    |

  10. For a reaction, pA + qB rarr products, the rate law expression is r = ...

    Text Solution

    |

  11. For the reaction, 4KClO3rarr3KClO4+KCl if (-d[KClO3])/(dt)=k1[KClO3]^4...

    Text Solution

    |

  12. The following data pertains to reaction between A and B. Whic...

    Text Solution

    |

  13. A reaction was found to be second order with respect to the concentrat...

    Text Solution

    |

  14. The following mechanism has been proposed for the reaction of NO with ...

    Text Solution

    |

  15. Consider the reaction, 2A + B rarr products. When concentration of D a...

    Text Solution

    |

  16. For a reaction, 1/2Ararr 2B rate of disappearance of A is related to t...

    Text Solution

    |

  17. For a pseudo first order reaction, CH3COOC2H5+H2Ooverset(H^(+))(hA...

    Text Solution

    |

  18. In the reaction, BrO(3(aq))^(-)+5Br((aq))^(-)+6H^(+)rarr3Br(2(l))+...

    Text Solution

    |

  19. For gaseous reactions, the rate is often expressed in terins of dP//dt...

    Text Solution

    |

  20. For a reaction A + B rarr Products, it is observed that doubling the c...

    Text Solution

    |