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Why formic acid reduces Tollen's reagent...

Why formic acid reduces Tollen's reagent like aldehydes?

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Reaction of HCOOH acid with Tollen.s reagent.
`HCOOH+2[Ag(NH_(3))_(2)]^(+)+2OH^(Theta)rarr2Ag+CO_(2)uarr+2H_(2)O+4NH_(3)`
Reaction of formic acid with sodium
`2HCOOH+2Nararr2HCOONa+H_(2)`
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How formic acid reacts with Tollen's reagent?

Knowledge Check

  • Tollen.s reagent is

    A
    ammoniacal cuprous chloride
    B
    ammonical cuprous oxide
    C
    ammoniacal silver bromide
    D
    ammoniacal silver nitrate
  • Tollen's reagent is :

    A
    Ammoniacal cuprous chloride
    B
    Ammoniacal cuprous oxide
    C
    Ammoniacal silver nitrate
    D
    Ammoniacal silver nitrate
  • Tollen.s reagent is :

    A
    Ammoniacal cuprous chloride
    B
    Ammoniacal cuprous oxide
    C
    Ammoniacal silver nitrate
    D
    Ammoniacal ferrous nitrate
  • ARIHANT PUBLICATION-CARBOXYLIC ACIDS -ODISHA BUREAU.S TEXTBOOK SOLUTIONS (C. SHORT ANSWER TYPE I QUESTIONS)
    1. Why formic acid reduces Tollen's reagent like aldehydes?

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    2. Explain why formic acid has two different C-O bond lengths i.e. 1.23Å ...

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    3. Give two tests to distinguish between formic acid and acetic acid.

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    4. How can you convert toluene into m-nitrobenzoic acid?

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    5. How formic acid can be converted to acetic acid?

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    6. What happens when acetic acid is treated with NH(4)OH and the product ...

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    7. Why m-nitrobenzoic acid is a stronger acid than benzoic acid?

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    8. Identify A and B C(6)H(5)COOHunderset("Conc. "H(2)SO(4))overset("Con...

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    9. What happens when acetamide is boiled with NaOH solution?

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    10. Identify A and B C(6)H(5)COOHoverset(SoCl(2))rarrAunderset(Pd//BaSO(...

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    11. Distinguish between acetic acid and ethanol?

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    12. Explain why the bond length of C-O in carboxylic acid is slightly larg...

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    13. What happens when sodium propionate is heated with sodalime?

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    14. What happens when acetic acid reacts with ethyl alcohol in presence of...

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    15. How acetic acid is prepared from methyl cyanide?

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    16. What happens when sodium acetate is heated with sodalime?

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    17. What happens when formic acid reacts with acidified KMnO(4) solution?

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    18. Explain acetic acid is stronger acid than ethanol.

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    19. What is the reaction of acetic acid with lime water?

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    20. How can you get acetone from acetic acid?

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