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compound X is tested and the results are...

compound X is tested and the results are shown in the following table.
`|{:("Test","Result",),("Aqueous NaOH is added and heated gently.","Gas released turns moist red litmus paper blue",),("Dilute HCl is added","Gas is evolved accompanied by brisk effervescence. It turns lime water milky and acidified " K_(2)Cr_(2)O_(7) " paper green.",):}|`
The compound X contains

A

Ammonium and suphite ions

B

Ammonium and carbonate ions

C

Sodium and carbonate ions

D

Ammonium and sulphate ions

Text Solution

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The correct Answer is:
To solve the problem regarding compound X and its tests, we will analyze the observations step by step. ### Step 1: Analyze the first test with Aqueous NaOH - **Observation**: When aqueous NaOH is added and heated gently, a gas is released that turns moist red litmus paper blue. - **Interpretation**: The gas released must be basic in nature since it turns red litmus paper blue. This indicates the presence of ammonia (NH₃) gas. **Reaction**: When ammonium ions (NH₄⁺) react with hydroxide ions (OH⁻) from NaOH, ammonia gas is produced: \[ NH_4^+ + OH^- \rightarrow NH_3(g) + H_2O \] ### Step 2: Analyze the second test with Dilute HCl - **Observation**: When dilute HCl is added, gas is evolved accompanied by brisk effervescence. The gas turns lime water milky and can also turn acidified potassium dichromate paper green. - **Interpretation**: The gas that evolves must be either carbon dioxide (CO₂) or sulfur dioxide (SO₂). The fact that it turns lime water milky suggests that it could be CO₂, but the additional observation of turning potassium dichromate paper green indicates it is likely SO₂, as SO₂ acts as a reducing agent. **Reactions**: 1. **Lime Water Test**: \[ Ca(OH)_2 + SO_2 \rightarrow CaSO_3 \, (s) \, \text{(which turns lime water milky)} \] 2. **Potassium Dichromate Test**: \[ K_2Cr_2O_7 + H_2SO_4 + SO_2 \rightarrow Cr_2(SO_4)_3 + K_2SO_4 + H_2O \] (This reaction shows that SO₂ reduces Cr₂O₇²⁻ to Cr³⁺, which is green in color.) ### Conclusion Based on the observations: - The first test indicates the presence of ammonium ions (NH₄⁺). - The second test indicates the presence of sulfite ions (SO₃²⁻), which produces SO₂ gas. Thus, compound X contains **ammonium ions (NH₄⁺)** and **sulfite ions (SO₃²⁻)**. ### Final Answer The compound X contains **ammonium ions (NH₄⁺) and sulfite ions (SO₃²⁻)**. ---

To solve the problem regarding compound X and its tests, we will analyze the observations step by step. ### Step 1: Analyze the first test with Aqueous NaOH - **Observation**: When aqueous NaOH is added and heated gently, a gas is released that turns moist red litmus paper blue. - **Interpretation**: The gas released must be basic in nature since it turns red litmus paper blue. This indicates the presence of ammonia (NH₃) gas. **Reaction**: When ammonium ions (NH₄⁺) react with hydroxide ions (OH⁻) from NaOH, ammonia gas is produced: ...
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