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HgCl(2) and I(2) both when dissolved in ...

`HgCl_(2)` and `I_(2)` both when dissolved in water containing `I^(-)`ions, the pair of species formed is :

A

`Hgl_(2),I^(-)`

B

`Hgl_(4)^(2-), I_(3)^(-)`

C

`Hg_(2)l_(2), I^(-)`

D

`Hgl_(2), I_(3)^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reactions that occur when `HgCl2` and `I2` are dissolved in water containing `I^(-)` ions. ### Step-by-Step Solution: 1. **Identify the compounds involved**: We have `HgCl2` (mercury(II) chloride) and `I2` (iodine) in the presence of `I^(-)` ions. 2. **Reaction of `HgCl2` with `I^(-)` ions**: - When `HgCl2` is added to a solution containing `I^(-)` ions, a complex ion is formed. The reaction can be represented as: \[ HgCl_2 + 4I^- \rightarrow HgI_4^{2-} + 2Cl^- \] - Here, `HgI4^{2-}` (tetraiodomercurate(II)) is formed along with `Cl^-` ions. 3. **Reaction of `I2` with `I^(-)` ions**: - When `I2` is added to the solution containing `I^(-)` ions, another species is formed. The reaction can be represented as: \[ I_2 + I^- \rightarrow I_3^- \] - In this reaction, the triiodide ion `I3^-` is formed. 4. **Summary of the species formed**: - From the reactions above, we have two species formed: - `HgI4^{2-}` - `I3^-` 5. **Conclusion**: - The pair of species formed when `HgCl2` and `I2` are dissolved in water containing `I^(-)` ions is `HgI4^{2-}` and `I3^-`. ### Final Answer: The pair of species formed is `HgI4^{2-}` and `I3^-`. ---

To solve the problem, we need to analyze the reactions that occur when `HgCl2` and `I2` are dissolved in water containing `I^(-)` ions. ### Step-by-Step Solution: 1. **Identify the compounds involved**: We have `HgCl2` (mercury(II) chloride) and `I2` (iodine) in the presence of `I^(-)` ions. 2. **Reaction of `HgCl2` with `I^(-)` ions**: - When `HgCl2` is added to a solution containing `I^(-)` ions, a complex ion is formed. The reaction can be represented as: ...
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