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When BaCl(2) is added to an aqueous salt...

When `BaCl_(2)` is added to an aqueous salt solution, a while precipitate is obtained. The anion among `CO_(3)^(2-), SO_(3)^(2-)` and `SO_(4)^(2-)` that was present in the solubtion can be :

A

`CO_(3)^(2-)` but not any of the other two

B

`SO_(3)^(2-)` but not any of the other two

C

`SO_(4)^(2-)` but not any of the other two

D

None of these

Text Solution

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The correct Answer is:
To solve the problem, we need to determine which anion among \( \text{CO}_3^{2-} \), \( \text{SO}_3^{2-} \), and \( \text{SO}_4^{2-} \) can form a white precipitate when \( \text{BaCl}_2 \) is added to an aqueous salt solution. ### Step-by-Step Solution: 1. **Identify the Reaction**: When \( \text{BaCl}_2 \) is added to the solution, the barium ions \( \text{Ba}^{2+} \) can react with the anions present in the solution to form precipitates. 2. **Consider Each Anion**: - **For \( \text{CO}_3^{2-} \)**: \[ \text{Ba}^{2+} + \text{CO}_3^{2-} \rightarrow \text{BaCO}_3 \, (\text{white precipitate}) \] - **For \( \text{SO}_3^{2-} \)**: \[ \text{Ba}^{2+} + \text{SO}_3^{2-} \rightarrow \text{BaSO}_3 \, (\text{white precipitate}) \] - **For \( \text{SO}_4^{2-} \)**: \[ \text{Ba}^{2+} + \text{SO}_4^{2-} \rightarrow \text{BaSO}_4 \, (\text{white precipitate}) \] 3. **Determine the Precipitate Color**: All three reactions produce a white precipitate: - \( \text{BaCO}_3 \) is a white solid. - \( \text{BaSO}_3 \) is also a white solid. - \( \text{BaSO}_4 \) is a well-known white precipitate. 4. **Conclusion**: Since all three anions can form white precipitates with \( \text{Ba}^{2+} \), we conclude that the anion present in the solution could be any of the three: \( \text{CO}_3^{2-} \), \( \text{SO}_3^{2-} \), or \( \text{SO}_4^{2-} \). 5. **Final Answer**: The correct answer is that the anion present in the solution can be \( \text{CO}_3^{2-} \), \( \text{SO}_3^{2-} \), or \( \text{SO}_4^{2-} \) since all can form white precipitates with \( \text{Ba}^{2+} \).

To solve the problem, we need to determine which anion among \( \text{CO}_3^{2-} \), \( \text{SO}_3^{2-} \), and \( \text{SO}_4^{2-} \) can form a white precipitate when \( \text{BaCl}_2 \) is added to an aqueous salt solution. ### Step-by-Step Solution: 1. **Identify the Reaction**: When \( \text{BaCl}_2 \) is added to the solution, the barium ions \( \text{Ba}^{2+} \) can react with the anions present in the solution to form precipitates. 2. **Consider Each Anion**: - **For \( \text{CO}_3^{2-} \)**: ...
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