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The hybridisation of oxygen in both wate...

The hybridisation of oxygen in both water and diethyl ether molecules is the same but they differ in their bond angles. Explain.

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To explain the difference in bond angles between water (H₂O) and diethyl ether (C₂H₅)₂O, despite having the same hybridization of oxygen, we can follow these steps: ### Step 1: Identify the Structures - Water (H₂O) has the following structure: - Oxygen is bonded to two hydrogen atoms and has two lone pairs of electrons. - Diethyl ether ((C₂H₅)₂O) has the following structure: - Oxygen is bonded to two ethyl groups (C₂H₅) and has two lone pairs of electrons. ...
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(a) Explain why cleavage of phenyl ethers with HBr always produces phenol and alkyl bromides and not bromobenzene and alkanols. (b) Give reasons for the following: (i) The dipole moment of diethyl ether (1.18D) is lower than that of water (1.84D). (ii) The C-O-C bond angle in ethers is higher than H-O-H angle in water though oxygen is sp3 hybridized in both the cases. (iii) Dimethyl ether is completely miscible with water but diethyl ether is soluble in water to a small extent.